Volume 18, Issue 33
Preparative Inorganic Chemistry
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ChemInform Abstract: Syntheses of New Uranium Complexes Cl2U(π-S4N4) and (C5H5)3UClAlCl3·THF.

C. C. CHANG

C. C. CHANG

Dep. Chem., Natl. Sun Yat-Sen Univ., Kaohsiung, Taiwan

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N. K. SUNG-YU

N. K. SUNG-YU

Dep. Chem., Natl. Sun Yat-Sen Univ., Kaohsiung, Taiwan

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C. W. KANG

C. W. KANG

Dep. Chem., Natl. Sun Yat-Sen Univ., Kaohsiung, Taiwan

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C. T. CHANG

C. T. CHANG

Dep. Chem., Natl. Sun Yat-Sen Univ., Kaohsiung, Taiwan

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First published: August 18, 1987

Abstract

The title complexes have been prepared as shown in the scheme.

ChemInform Abstract

The title complexes have been prepared as shown in the scheme. The compounds are characterized by 14N-, 27Al-, and 1H-NMR, and IR spectroscopy as well as by cyclic voltammetry. (VII) is suggested to have a square bipyramidal configuration with THF in the sixth position to form an octahedral structure.

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