Volume 18, Issue 16
Organoelement Compounds
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ChemInform Abstract: Transition Metal Alkyl Compounds. Part 48. Synthesis and Properties of Tetrakis(1-naphthylmethyl) Titanium, Zirconium, and Hafnium.

J. SCHOLZ

J. SCHOLZ

Sekt. Chem., Tech. Hochsch. "Carl Schorlemmer", DDR-4200 Merseburg

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K.-H. THIELE

K.-H. THIELE

Sekt. Chem., Tech. Hochsch. "Carl Schorlemmer", DDR-4200 Merseburg

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First published: April 21, 1987

Abstract

The title compounds (II) are prepared by 4:1 molar reaction of 1-naphthylmethyl-MgCl (I) with the metal tetrachlorides as shown.

ChemInform Abstract

The title compounds (II) are prepared by 4:1 molar reaction of 1-naphthylmethyl-MgCl (I) with the metal tetrachlorides as shown. Their properties are compared to those of corresponding tetrabenzyl derivatives. The new compounds are characterized by hydrolysis and thermolysis reactions, and by IR, 1H NMR, and mass spectra.

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