Volume 17, Issue 50
Isocyclic Compounds
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ChemInform Abstract: Co(II)Porphyrin Catalyzed Isomerization of Bicyclobutanecarbonitrile.

First published: December 16, 1986

Abstract

The bicyclobutane carboxylic acid derivatives (Ib) and (Ie) isomerize in the presence of Co(II) porphyrin yielding the cyclobutene compounds (II).

ChemInform Abstract

The bicyclobutane carboxylic acid derivatives (Ib) and (Ie) isomerize in the presence of Co(II) porphyrin yielding the cyclobutene compounds (II). Using the same reaction conditions, the methylated derivatives (Ic) and (Id)′don′t react, (Ic) gives polymeric products. (NMR-, MS- data).

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