Volume 17, Issue 44
Heterocyclic Compounds
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ChemInform Abstract: Palladium Catalysis in the Synthesis of Indoloquinones.

First published: November 4, 1986

Abstract

The indoles (I) and (V) react readily with methyl acrylate (II) under Pd catalysis to give the corresponding insertion products (III), (IV) and (VI).

ChemInform Abstract

The indoles (I) and (V) react readily with methyl acrylate (II) under Pd catalysis to give the corresponding insertion products (III), (IV) and (VI). Attempts to prepare pyrroloindoles by an intramolecular reaction of (I) or (V), however, are not successful. These reactions are part of a review of the palladium-catalysed synthesis of indoloquinones (17 refs.).

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