Racemization Mechanisms and Chemistry of D-Amino Acids
Amino Acid Ligand Chirality for Enantioselective Syntheses
Károly Micskei,
Tamás Patonay,
Luciano Caglioti,
Gyula Pályi,
Károly Micskei
Institute of Chemistry, University of Debrecen, Egyetem tér 1, H-4032 Debrecen
Search for more papers by this authorTamás Patonay
Institute of Chemistry, University of Debrecen, Egyetem tér 1, H-4032 Debrecen
Search for more papers by this authorLuciano Caglioti
Department of Chemistry and Technology of Biologically Active Compounds, University ‘La Sapienza'-Roma, Ple. A. Moro 5, I-00185 Roma
Search for more papers by this authorGyula Pályi
Department of Chemistry. University of Modena and Reggio Emilia, I-41100 Modena
Search for more papers by this authorKároly Micskei,
Tamás Patonay,
Luciano Caglioti,
Gyula Pályi,
Károly Micskei
Institute of Chemistry, University of Debrecen, Egyetem tér 1, H-4032 Debrecen
Search for more papers by this authorTamás Patonay
Institute of Chemistry, University of Debrecen, Egyetem tér 1, H-4032 Debrecen
Search for more papers by this authorLuciano Caglioti
Department of Chemistry and Technology of Biologically Active Compounds, University ‘La Sapienza'-Roma, Ple. A. Moro 5, I-00185 Roma
Search for more papers by this authorGyula Pályi
Department of Chemistry. University of Modena and Reggio Emilia, I-41100 Modena
Search for more papers by this authorAbstract
Amino acids are attractive sources of chirality in stoichiometric or catalytic transition metal/organic chemistry. In spite of easy availability and other advantages, the application of these ligands is hindered by several problems. Now, at the dawn of emerging d-amino acid biochemistry, efforts in this direction are becoming increasingly important. The results of research on application of amino acid ligands for transition-metal reagents in organic syntheses are reviewed in the present work.
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