The Shear Viscosity of Liquid Hg Based Alloys Containing In
M. Nozaki
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Search for more papers by this authorY. Morikawa
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Search for more papers by this authorT. Itami
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Search for more papers by this authorM. Shimoji
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Search for more papers by this authorM. Nozaki
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Search for more papers by this authorY. Morikawa
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Search for more papers by this authorT. Itami
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Search for more papers by this authorM. Shimoji
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Search for more papers by this authorAbstract
The shear viscosity η was measured as a detailed function of composition for liquid Hg based alloys containing 0–16 at% In in the temperature range from 320 K. to 520 K. A capillary viscometer of the Ostwald type was used for measurements. — The η increases linearly with the addition of In. This concentration dependence could be well explained by a simple hard sphere theory for η of liquid mixtures, in which the correction of back scattering took an important role. — The isothermal curves of ∂η/∂T show a slight depression at a few at% In, particularly at lower temperatures. This phenomenon appears to be related to higher order correlation (HOC) effects, which have been proposed recently for some liquid Hg based alloys by the present authors.
References
- 1 T. Itami, T. Wada, and M. Shimoji, J. Phys. F: Met. Phys. 12, 1959 (1982).
- 2 T. Itami, N. Takahashi, and M. Shimoji, J. Phys. F: Met. Phys. 13, 1225 (1983).
- 3 T. Itami, S. Takahashi, and M. Shimoji, J. Phys. F: Met. Phys. 14, 427 (1984).
- 4 Y. Morikawa, T. Itami, and M. Shimoji, J. Phys. F: Met. Phys. 16, 1385 (1986).
- 5 Y. Okajima and M. Shimoji, Trans. Jpn. Inst. Met. 13, 255 (1972).
- 6 S. Takeuchi, Z. Morita, and T. Iida, Trans. Jpn. Inst. Met. 35, 218 (1971).
- 7 A. Kasama, T. Iida, and Z. Morita, Trans. Jpn. Inst. Met. 16, 527 (1975).
- 8
M. Bosco Masera
and
R. Malvano,
Phys. Chem. Liq.
5,
151
(1976).
10.1080/00319107608084115 Google Scholar
- 9 M. Bosco Masera and R. Malvano, Phys. Chem. Liq. 9, 143 (1980).
- 10 M. Kitajima, K. Saito, and M. Shimoji, Trans. Jpn. Inst. Met. 17, 582 (1976).
- 11 R. T. Beyer and E. M. Ring, “Liquid Metals”, Ed. S. Z. Beer, p. 431, Marcel Dekker, 1972.
- 12
M. Shimoji
and
T. Itami,
“ Atomic Transport in Liquid Metals”,
Trans. Tech. Publications
1986.
10.4028/b-dcLJp3 Google Scholar
- 13 S. Erk, Z. Phys. 47, 886 (1928).
- 14 P. H. Bigg, Brit. J. Appl. Phys. 15, 1111 (1964).
- 15 H. A. Davies, P. H. Draper, and J. S. Ll. Leach, Phys. Chem. Liq. 1, 171 (1968).
- 16 M. Plüss, Z. Anorg. Allg. Chem. 93, 1 (1915).
- 17 A. V. Grosse, J. Phys. Chem. 68, 3419 (1964).
- 18 J. M. Grouvel, J. Kestin, H. E. Khalifa, E. V. Frank, and F. Hensel, Ber. Bunsenges. Phys. Chem. 81, 338 (1977).
- 19 J. A. Cahill and A. V. Grosse, J. Phys. Chem. 69, 518 (1965).
- 20 E. A. Moelwyn-Hughes, “ Physical Chemistry”, Pergamon Press 1961.
- 21 R. Hultgren, P. D. Desai, D. T. Hawkins, M. Gleiser, and K. K. Kelly, “ Selected Values of the Thermodynamic Properties of Binary Alloys”, American Society for Metals 1973.
- 22 M. Kitajima, T. Itami, and M. Shimoji, Phil. Mag. 30, 285 (1974).
- 23 M. Shimoji, “Liquid Metals”, Academic Press, London and New York 1977.
- 24 H. C. Longuet-Higgins and J. A. Pople, J. Chem. Phys. 25, 884 (1956).
- 25 T. E. Faber, “ Introduction to the Theory of Liquid Metals”, Cambridge University Press 1972.
- 26 B. J. Alder, D. M. Gass, and T. E. Wainwright, J. Chem. Phys. 53, 3813 (1970).
- 27 T. Naitoh and S. Ono, Phys. Lett. 57A, 448 (1976). See also T. Naitoh and S. Ono, Phys. Lett. 69A, 125 (1978) and J. Chem. Phys. 70, 4515 (1979).
- 28 S. Chapman and T. G. Cowling, “ The Mathematical Theory of Non-Uniform Gases”, Cambridge University Press 1970.
- 29 T. Gaskell, J. Phys. C: Solid State Phys. 7, 1631 (1974).
- 30 J. L. Lebowitz, Phys. Rev. 133, ( A 895 (1964).
- 31 P. Protopapas, H. C. Anderson, and N. A. D. Parlee, J. Chem. Phys. 59, 15 (1973).
- 32 F. P. Buff and R. Brout, J. Chem. Phys. 23, 458 (1955).
- 33 Y. Morikawa, T. Itami, and M. Shimoji, Ber. Bunsenges. Phys. Chem. 90, 1174 (1986).
