Copolymerization of catechol and polyethyleneimine onto activated carbon for efficient removal of Congo red dye
Dexiang Yan
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
Search for more papers by this authorFenghua Li
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
Search for more papers by this authorBin Sun
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
Search for more papers by this authorYuanbo Wang
Shandong Land and Space Ecological Restoration Center, Jinan, China
Search for more papers by this authorQinze Liu
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
Search for more papers by this authorCorresponding Author
Tingting Gao
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
Correspondence
Tingting Gao, Daxue Road, Western University Science Park, Jinan 250353, Shandong, China.
Email: [email protected]
Search for more papers by this authorGuowei Zhou
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
Search for more papers by this authorDexiang Yan
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
Search for more papers by this authorFenghua Li
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
Search for more papers by this authorBin Sun
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
Search for more papers by this authorYuanbo Wang
Shandong Land and Space Ecological Restoration Center, Jinan, China
Search for more papers by this authorQinze Liu
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
Search for more papers by this authorCorresponding Author
Tingting Gao
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
Correspondence
Tingting Gao, Daxue Road, Western University Science Park, Jinan 250353, Shandong, China.
Email: [email protected]
Search for more papers by this authorGuowei Zhou
Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, China
Search for more papers by this authorFunding information: Opening program of State Key Laboratory of Solid Lubrication, Grant/Award Number: LSL-1904; Program for Scientific Research Innovation Team in Colleges and Universities of Jinan, Grant/Award Number: 2018GXRC006; Key Technology Research and Development Program of Shandong, Grant/Award Numbers: 2019GGX102027, 2019GGX102070; National Natural Science Foundation of China, Grant/Award Numbers: 51572134, 51972180; Natural Science Foundation of Shandong Province, Grant/Award Numbers: ZR2019BB030, ZR2020ME082
Abstract
In this work, a new AC@Catechol/PEI adsorbent was prepared via the copolymerization of catechol and polyethyleneimine (PEI) onto pretreated commercial activated carbon (AC). It achieved a high adsorption capacity of 411.52 mg/g for the anionic dye Congo red (CR), which was approximately 7 times that of pretreated AC without modification. In bath adsorption experiment, 1 g of adsorbent was used to treat 4 L of 100 mg/L CR solution, resulting in 98.5% CR removal. In addition, the prepared AC@Catechol/PEI adsorbent exhibited highly efficient CR competitive adsorption against SO42− ions and cationic malachite green dye. The adsorption mechanism was mainly attributed to electrostatic interactions, hydrogen bonding, and π–π stacking. Catecholamine modification greatly improved the adsorption capacity and adsorption selectivity of commercial AC for CR dyes. This low-cost adsorbent may have broad prospects for the removal of anionic dyes in wastewater.
Open Research
DATA AVAILABILITY STATEMENT
No. Research data are not shared.
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