High shape-memory effect of hindered phenol/nitrile–butadiene rubber composites by forming hydrogen bonding
Shi-Kai Hu
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
SINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013 China
Search for more papers by this authorTao Shou
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Search for more papers by this authorSi Chen
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Search for more papers by this authorCorresponding Author
Xiu-Ying Zhao
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Correspondence to: X. Y. Zhao (E-mail: [email protected]) and Y. L. Lu (E-mail: [email protected])Search for more papers by this authorCorresponding Author
Yong-Lai Lu
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Correspondence to: X. Y. Zhao (E-mail: [email protected]) and Y. L. Lu (E-mail: [email protected])Search for more papers by this authorLi-Qun Zhang
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Search for more papers by this authorShi-Kai Hu
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
SINOPEC Beijing Research Institute of Chemical Industry, Beijing, 100013 China
Search for more papers by this authorTao Shou
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Search for more papers by this authorSi Chen
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Search for more papers by this authorCorresponding Author
Xiu-Ying Zhao
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Correspondence to: X. Y. Zhao (E-mail: [email protected]) and Y. L. Lu (E-mail: [email protected])Search for more papers by this authorCorresponding Author
Yong-Lai Lu
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Correspondence to: X. Y. Zhao (E-mail: [email protected]) and Y. L. Lu (E-mail: [email protected])Search for more papers by this authorLi-Qun Zhang
Key Lab of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing, 100029 China
Search for more papers by this authorABSTRACT
To widen the type and scope of use of shape memory polymers (SMPs), we added hindered phenol (AO-80) to nitrile–butadiene rubber (NBR) to gain a group of AO-80/NBR rubber composites. The glass transition temperature (Tg), structure, mechanical properties, and shape memory properties of the AO-80/NBR rubber composites were characterized. It was concluded that the dispersion of AO-80 in the NBR matrix was homogeneous and intra-molecular hydrogen bonds were formed between the hydroxyl groups (OH) of AO-80 and the cyano groups (CN) of NBR molecular chain. The dosage of AO-80 added could be changed to tune the Tg. AO-80/NBR rubber composites revealed outstanding shape fixity and shape recovery. The method for tuning the Tg of AO-80/NBR rubber composites will provide an idea for the fabrication and design of new SMPs. © 2020 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48911.
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