CuS-functionalized cellulose based aerogel as biocatalyst for removal of organic dye
Rana Muhammad Yousaf Saeed
Biofuels Institute, School of the Environment, Jiangsu University, Zhenjiang, 212013 China
Search for more papers by this authorZahira Bano
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 China
Search for more papers by this authorJianzhong Sun
Biofuels Institute, School of the Environment, Jiangsu University, Zhenjiang, 212013 China
Search for more papers by this authorFengyun Wang
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 China
Search for more papers by this authorNabi Ullah
School of Chemical Engineering, Jiangsu University, Zhenjiang, 212013 China
Search for more papers by this authorCorresponding Author
Qianqian Wang
Biofuels Institute, School of the Environment, Jiangsu University, Zhenjiang, 212013 China
State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640 China
Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Key Laboratory of Biomass Energy and Material, Jiangsu Province, Nanjing, 210042 China
Correspondence to: Q. Wang (E-mail: [email protected])Search for more papers by this authorRana Muhammad Yousaf Saeed
Biofuels Institute, School of the Environment, Jiangsu University, Zhenjiang, 212013 China
Search for more papers by this authorZahira Bano
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 China
Search for more papers by this authorJianzhong Sun
Biofuels Institute, School of the Environment, Jiangsu University, Zhenjiang, 212013 China
Search for more papers by this authorFengyun Wang
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 China
Search for more papers by this authorNabi Ullah
School of Chemical Engineering, Jiangsu University, Zhenjiang, 212013 China
Search for more papers by this authorCorresponding Author
Qianqian Wang
Biofuels Institute, School of the Environment, Jiangsu University, Zhenjiang, 212013 China
State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640 China
Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Key Laboratory of Biomass Energy and Material, Jiangsu Province, Nanjing, 210042 China
Correspondence to: Q. Wang (E-mail: [email protected])Search for more papers by this authorABSTRACT
CuS-functionalized cellulose based aerogel (CBA) with 3D macroporous structure was synthesized by in situ deposition of visible light responsive CuS photocatalyst. Hexagonal CuS was deposited onto the outer and inner walls of CBA matrix. CuS/CBA composite catalyst has hierarchical porous structure and abundance in functional groups supporting CuS on CBA surface that enhance photodecomposition of methylene blue (MB). The CuS/CBA composite was characterized by XRD, FTIR, SEM-EDS, Atomic Absorption Analysis, and XPS analysis. Photodegradation rate of MB by CuS/CBA composite catalyst in visible light was 94.1%, whereas, 67.4% for pure CuS. Initial MB concentration effects, pH change, and variations in CuS/CBA dosage on overall reaction kinetics were also studied. CuS/CBA composite catalyst carried out Photo-Fenton like reactions which decomposed 97% MB within 6 min, by producing hydroxyl radicals from chemical and photocatalytic reactions. CuS/CBA composite catalyst was recycled and reused. It retained over 80% MB degradation rate even after five consecutive cycles. CuS/CBA composite can be used as biocatalyst for removal of organic dyes. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47404.
Supporting Information
| Filename | Description |
|---|---|
| app47404-sup-0001-FigureS1.docxWord 2007 document , 76.5 KB | Figure S1 Adsorption of MB on CuS, CBc100 and CBA, initial MB concentration 20 mg L-1, ambient temperature, pH 6.8 |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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