Permeation of hydrocarbons through organosilane crosslinked LDPE
Katrin Berger
Polymer Competence Center Leoben GmbH, Leoben, 8700 Austria
Search for more papers by this authorChristian Keimel
Polymer Competence Center Leoben GmbH, Leoben, 8700 Austria
Search for more papers by this authorEric Helfer
Chair in Chemistry of Polymeric Materials, Montanuniversitaet Leoben, Leoben, 8700 Austria
Search for more papers by this authorBernd Haar
Polymer Competence Center Leoben GmbH, Leoben, 8700 Austria
Search for more papers by this authorAlexander Eder
Chair in Polymer Processing, Montanuniversitaet Leoben, Leoben, 8700 Austria
Search for more papers by this authorHannelore Mattausch
Chair in Polymer Processing, Montanuniversitaet Leoben, Leoben, 8700 Austria
Search for more papers by this authorCorresponding Author
Gisbert Riess
Chair in Chemistry of Polymeric Materials, Montanuniversitaet Leoben, Leoben, 8700 Austria
Correspondence to: G. Riess (E-mail: [email protected])Search for more papers by this authorKatrin Berger
Polymer Competence Center Leoben GmbH, Leoben, 8700 Austria
Search for more papers by this authorChristian Keimel
Polymer Competence Center Leoben GmbH, Leoben, 8700 Austria
Search for more papers by this authorEric Helfer
Chair in Chemistry of Polymeric Materials, Montanuniversitaet Leoben, Leoben, 8700 Austria
Search for more papers by this authorBernd Haar
Polymer Competence Center Leoben GmbH, Leoben, 8700 Austria
Search for more papers by this authorAlexander Eder
Chair in Polymer Processing, Montanuniversitaet Leoben, Leoben, 8700 Austria
Search for more papers by this authorHannelore Mattausch
Chair in Polymer Processing, Montanuniversitaet Leoben, Leoben, 8700 Austria
Search for more papers by this authorCorresponding Author
Gisbert Riess
Chair in Chemistry of Polymeric Materials, Montanuniversitaet Leoben, Leoben, 8700 Austria
Correspondence to: G. Riess (E-mail: [email protected])Search for more papers by this authorABSTRACT
The importance of polymeric transportation systems has been steadily increasing over the years. It is a useful material in numerous applications, such as packaging, oil and gas pipes, and household items. One particular aspect of polyethylene (PE) is the permeability of small molecules, such as low-molecular-weight hydrocarbons. In the present study, PE sheets were crosslinked by grafting and subsequent hydrolysis of organosilanes during a reactive extrusion process. The formation of a network structure was characterized by sol/gel analysis and by rheological measurements. It is shown that as a result of crosslinking the permeation of linear alkanes through the PE is reduced. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45374.
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