Multifunctional epoxy resin/polyacrylonitrile-lithium trifluoromethanesulfonate composites films with very high transparency, high dielectric permittivity, breakdown strength and mechanical properties
Sheng Sun
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorLonghui Zheng
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorLi Yuan
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorQingbao Guan
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorCorresponding Author
Guozheng Liang
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Correspondence to: A. Gu (E-mail: [email protected]) and G. Liang (E-mail: [email protected])Search for more papers by this authorCorresponding Author
Aijuan Gu
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Correspondence to: A. Gu (E-mail: [email protected]) and G. Liang (E-mail: [email protected])Search for more papers by this authorSheng Sun
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorLonghui Zheng
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorLi Yuan
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorQingbao Guan
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Search for more papers by this authorCorresponding Author
Guozheng Liang
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Correspondence to: A. Gu (E-mail: [email protected]) and G. Liang (E-mail: [email protected])Search for more papers by this authorCorresponding Author
Aijuan Gu
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 China
Correspondence to: A. Gu (E-mail: [email protected]) and G. Liang (E-mail: [email protected])Search for more papers by this authorABSTRACT
Multifunctional transparent composite films with high dielectric permittivity (high-k), breakdown strength, and mechanical properties are urgently required by cutting-edge fields. Herein, novel multifunctional films were facilely prepared through building unique cross-linked structure based on epoxy resin (EP) and polyacrylonitrile (PAN)-lithium trifluoromethane sulfonate (LiTf) complex. Compared with high-k materials reported previously, EP/(PAN-LiTf) films simultaneously show very high transparency, good flexibility, high tensile, and breakdown strengths. For 0.22EP/(PAN-LiTf) film with 22 wt % EP, its average transmittance and elongation at break are as high as 91% (600–800 nm) and 12.7%, respectively; moreover, its dielectric permittivity, AC breakdown strength and the maximum energy density are severally about 4.9, 1.8, and 15.2 times of those of EP resin, completely overcoming the sticky problems in conductor/polymer composites. The origin behind these attractive properties is intensively discussed, and believed to be attributed to the unique structure of EP/(PAN-LiTf) films. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45218.
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