Gas-sensor fabrication by a layer-by-layer technique using polydiacetylene
Minhee Kim
Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk, 28644 Korea
M. Kim and Y. J. Shin contributed equally to this work
Search for more papers by this authorYoung Jae Shin
Department of Physics, Harvard University, Cambridge, Massachusetts, 02138
M. Kim and Y. J. Shin contributed equally to this work
Search for more papers by this authorCorresponding Author
Min Jae Shin
School of Integrated Oriental Medical Bioscience, Semyung University, Jecheon, Chungbuk, 27136 Korea
Correspondence to: M. J. Shin (E-mail: [email protected]) and J. S. Shin (E-mail: [email protected])Search for more papers by this authorCorresponding Author
Jae Sup Shin
Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk, 28644 Korea
Correspondence to: M. J. Shin (E-mail: [email protected]) and J. S. Shin (E-mail: [email protected])Search for more papers by this authorMinhee Kim
Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk, 28644 Korea
M. Kim and Y. J. Shin contributed equally to this work
Search for more papers by this authorYoung Jae Shin
Department of Physics, Harvard University, Cambridge, Massachusetts, 02138
M. Kim and Y. J. Shin contributed equally to this work
Search for more papers by this authorCorresponding Author
Min Jae Shin
School of Integrated Oriental Medical Bioscience, Semyung University, Jecheon, Chungbuk, 27136 Korea
Correspondence to: M. J. Shin (E-mail: [email protected]) and J. S. Shin (E-mail: [email protected])Search for more papers by this authorCorresponding Author
Jae Sup Shin
Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk, 28644 Korea
Correspondence to: M. J. Shin (E-mail: [email protected]) and J. S. Shin (E-mail: [email protected])Search for more papers by this authorABSTRACT
In order to increase the sensitivity of a polydiacetylene (PDA) sensor, PDA, and poly(sodium 4-styrene-sulfonate) (PSS) were alternately stacked to form a layer-by-layer (LBL) film on the quartz. In this study, N-(2-aminoethyl)pentacosa-10,12-diynamide (AEPCDA) was used as a constituent of the PDA and n-butylamine was used as a target compound. The formed-film sensor showed higher sensitivity than the vesicle solution. There was a large difference in sensitivity depending on the method used to form the LBL film. Unlike the vesicle solution state, the formed-film sensor exhibited excellent reversibility in the color change caused by heat. The LBL film formed worked very well as a sensor that detects the actual gas, n-butyl amine, showing its potential for practical applications. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44997.
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July 10, 2017
