Composite sodium p-toluene sulfonate–polypyrrole–iron anode for a lithium-ion battery
Qishu Liao
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorCorresponding Author
Hongying Hou
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Correspondence to: H. Hou (E-mail: [email protected] or [email protected])Search for more papers by this authorJixiang Duan
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorSong Liu
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorYuan Yao
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorZhipeng Dai
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorChengyi Yu
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorDongdong Li
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorQishu Liao
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorCorresponding Author
Hongying Hou
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Correspondence to: H. Hou (E-mail: [email protected] or [email protected])Search for more papers by this authorJixiang Duan
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorSong Liu
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorYuan Yao
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorZhipeng Dai
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorChengyi Yu
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorDongdong Li
Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming, 650093 China
Search for more papers by this authorABSTRACT
In this study, p-toluene sulfonate (TsONa) doped polypyrrole (PPy) was synthesized for an anode in a lithium-ion battery via a one-step facile electropolymerization on Fe foil. The obtained TsONa–PPy–Fe composite electrode was investigated with scanning electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, and galvanostatic charge–discharge profiling. As expected, many irregular microspherical particles of TsONa-doped PPy formed and combined tightly with the surface of Fe foil. Furthermore, the obtained TsONa–PPy–Fe anode also delivered satisfactory electrochemical performances. For example, the reversible capacity was still about 105–115 mAh/g, even after at least 50 cycles. The high lithium storage activity of PPy and the high conductivity of the TsONa-doped PPy jointly contributed into the satisfactory electrochemical performances. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44935.
REFERENCES
- 1 Goodenough, J. B.; Park, K. S. J. Am. Chem. Soc. 2013, 135, 1167.
- 2 Duan, J.; Hou, H.; Liu, X.; Liu, S.; Liao, Q.; Yao, Y. Ceram. Int. 2016, 42, 16611.
- 3 Meng, R.; Hou, H.; Liu, X.; Hu, W.; Duan, J.; Liu, S. Ceram. Int. 2015, 41, 9988.
- 4 Jiang, H.; Hu, Y.; Guo, S.; Yan, C.; Lee, P.; Li, C. ACS Nano 2014, 8, 6038.
- 5 Chen, X.; Huang, Y.; Zhang, X.; Li, C.; Chen, J.; Wang, K. Mater. Lett. 2015, 152, 181.
- 6 Novak, P.; Mueller, K.; Santhanam, K. S. V.; Haas, O. Chem. Rev. 1997, 97, 207.
- 7 Otero, T. F.; Cantero, I. J. Power Sources 1999, 81, 838.
- 8 Bengoechea, M.; Boyano, I.; Miguel, O.; Cantero, I.; Ochoteco, E.; Pomposo, J.; Grandea, H. J. Power Sources 2006, 160, 585.
- 9 Zhao, Y.; Liu, J.; Hu, Y.; Cheng, H.; Hu, C.; Jiang, C.; Jiang, L.; Cao, A.; Qu, L. Adv. Mater. 2013, 25, 591.
- 10 Fonner, J. M.; Schmidt, C. E.; Ren, P. Polymer 2010, 51, 4985.
- 11 Su, W.; Iroh, J. O. Electrochim. Acta 2000, 46, 1.
- 12 Su, N.; Li, H. B.; Yuan, S. J.; Yi, S. P. Express Polym. Lett. 2012, 6, 697.
- 13 Kojabad, Z. D.; Shojaosadati, S. A. Mater. Des. 2016, 96, 378.
- 14 Zhao, Y.; Si, S.; Wang, L.; Liao, C.; Tang, P.; Cao, H. J. Power Sources 2014, 248, 962.
- 15 Ouyang, J.; Li, Y. Polymer 1997, 38, 3997.
- 16 Duan, J.; Hou, H.; Liu, X.; Liao, Q.; Liu, S.; Meng, R.; Hao, Z.; Yao, Y. J. Appl. Polym. Sci. 2016, 29, DOI: 10.1002/app.43685.
- 17 Yang, Y.; He, K.; Yan, P.; Wang, D.; Wu, X.; Zhao, X.; Huang, Z.; Zhang, C.; Huang, D. Electrochim. Acta 2014, 138, 481.
- 18 Grubac, Z.; Roncevic, I. S.; Metikos-Hukovic, M. Corros. Sci. 2015, 102, 310.
- 19 Shapiro, J. S.; Smith, W. T. Polymer 1993, 34, 4336.
- 20 Silverstein, R. M.; Webster, F. X. Spectroscopic Identification of Organic Compounds, 6th ed.; Wiley: New York, 1997.
- 21 Afshar, A.; Sadjadi, S. A. S.; Mollahosseini, A.; Eskandarian, M. R. Kor. J. Chem. Eng. 2016, 33, 669.
- 22 Kasisomayajula, S. V.; Qi, X.; Vetter, C.; Croes, K.; Pavlacky, D.; Gelling, V. J. J. Coat. Technol. Res. 2010, 7, 145.
- 23 Kumar, R.; Sekhon, S. S. Ionics 2013, 19, 1627.
- 24 Kumar, R.; Sharma, J. P.; Sekhon, S. Eur. Polym. J. 2005, 41, 2718.
- 25 Kasisomayajula, S.; Jadhav, N.; Gelling, V. RSC Adv. 2015, 6, 522.
- 26 Blinova, N. V.; Stejskal, J.; Trchova, M.; Prokes, J.; Omastova, M. Eur. Polym. J. 2007, 43, 2331.
- 27 Jang, W.; Sundar, S.; Choi, S.; Shul, Y.; Han, H. J. Membr. Sci. 2006, 280, 321.
- 28 Hazarika, J.; Kumar, A. Phys. Rev. B 2015, 138, 75.
- 29 Zhao, Y.; Zhu, W.; Chen, G. Z.; Cairns, E. S. J. Power Sources 2016, 327, 447.
- 30 Carrasco, P. M.; Grande, H. J.; Cortazar, M.; Alberdi, J. M.; Areizaga, J.; Pomposo, J. A. Synth. Met. 2006, 156, 420.
- 31 Sultana, I.; Rahman, M. M.; Wang, J.; Wang, G.; Wallace, G. G. Electrochim. Acta 2012, 83, 209.
- 32 Li, Y.; Fan, Y. Synth. Met. 1996, 79, 225.
- 33 Ju, Y. W.; Park, J. H.; Jung, H. R.; Lee, W. J. Electrochim. Acta 2007, 52, 4841.
- 34 Zhu, L.; Shen, Y.; Sun, M.; Qian, J.; Cao, Y.; Ai, X.; Yang, H. Chem. Commun. 2013, 49, 11370.
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20 June 2017
