Superparamagnetic iron oxide (SPIO) incorporated polystyrene beads of uniform size distribution (∼170 nm) and high magnetic content (∼40%) are synthesized by emulsion styrene polymerization in the presence of functionalized SPIO. The role of surface functionality on the polymerization process and SPIO incorporation is investigated by carrying out styrene emulsion polymerizations with different functionalities on SPIO. A unique combination of oleic acid and (2-acetoacetoxy) ethyl methacrylate as surface ligands for SPIO is used to attain the best magnetic beads. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

References

1 Haukanes, B. I.; Kvam, C. Nat. Biotechnol. 1993, 11, 60.
10.1038/nbt0193-60
CAS PubMed Web of Science® Google Scholar
2 Rahman, M. M.; Elaissari, A. J. Colloid Sci. Biotechnol. 2012, 1, 3.
10.1166/jcsb.2012.1006
CAS Google Scholar
3 Arkhis, A.; Elaissari, A.; Delair, T.; Verrier, B.; Mandrand, B. J. Biomed. Nanotechnol. 2010, 6, 28.
10.1166/jbn.2010.1093
CAS PubMed Web of Science® Google Scholar
4 Weddemann, A.; Wittbracht, F.; Auge, A.; Hütten, A. Appl. Phys. Lett. 2009, 94, 173501.
10.1063/1.3123809
CAS Web of Science® Google Scholar
5 Tarn, M. D.; Peyman, S.A. Robert, D.; Iles, A.; Wilhelm, C.; Pamme, N. J. Magn. Magn. Mater. 2009, 321, 4115.
10.1016/j.jmmm.2009.08.016
CAS Web of Science® Google Scholar
6 Laurent, S.; Forge, D.; Port, M.; Roch, A.; Robic, C.; Vander Elst, L.; Muller, R. N. Chem. Rev. 2008, 108, 2064.
10.1021/cr068445e
CAS PubMed Web of Science® Google Scholar
7 Zhao, W.; Shi, J.; Chen, H.; Zhang, L. J. Mater. Res. 2006, 21, 3080.
10.1557/jmr.2006.0381
CAS Web of Science® Google Scholar
8 Ma, D.; Veres, T.; Clime, L.; Normandin, F.; Guan, J.; Kingston, D.; Simard, B. J. Phys. Chem. C 2007, 111, 1999.
10.1021/jp0665067
CAS Web of Science® Google Scholar
9 Insin, N.; Tracy, J. B.; Lee, H.; Zimmer, J. P.; Westervelt, R. M.; Bawendi, M. G. ACS Nano 2008, 2, 197.
10.1021/nn700344x
CAS PubMed Web of Science® Google Scholar
10 Choi, W.-S.; Koob, H.-Y.; Huck, W.T. S. J. Mater. Chem. 2007, 17, 4943.
10.1039/b712455d
CAS Web of Science® Google Scholar
11 Sun, Y.; Duan, L.; Guo, Z.; DuanMu, Y.; Ma, M.; Xu, L.; Zhang, Y.; Gu, N. J. Magn. Magn. Mater. 2005, 285, 65.
10.1016/j.jmmm.2004.07.016
CAS Web of Science® Google Scholar
12 Zhou, X.; Kobayashi, Y.; Romanyuk, V.; Ochuchic, N.; Takedac, M.; Tsunekawad, S.; Kasuya, A. Appl. Surf. Sci. 2005, 242, 281.
10.1016/j.apsusc.2004.08.022
CAS Web of Science® Google Scholar
13 Steitz, B.; Krauss, F.; Rousseau, S.; Hofmann, H.; Petri-Fink, A. Adv. Eng. Mater. 2007, 9, 375.
10.1002/adem.200700052
CAS Web of Science® Google Scholar
14 Lou, M.-Y.; Jia, Q.-L.; Wang, De-P.; Liu, B.; Huang. W.-H. J. Mater. Sci: Mater. Med. 2008, 19, 217.
10.1007/s10856-007-3094-6
CAS PubMed Web of Science® Google Scholar
15 Montagne, F.; Mondain-Monval, O.; Pichot, C.; Elaïssari, A. J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 2642.
10.1002/pola.21391
CAS Web of Science® Google Scholar
16 Kondo, A.; Kamura, H.; Higashitani, K. Appl. Microbiol. Biotechnol. 1994, 41, 99.
10.1007/BF00166089
CAS PubMed Web of Science® Google Scholar
17 HoraK, D.; Semenyuk, N.; Lednický, F. J. Polym. Sci., Part A: Polym. Chem. 2003, 41, 1848.
10.1002/pola.10728
CAS Web of Science® Google Scholar
18 Niu, M.; Du, M.; Gao, Z.; Yang, C.; Lu, X.; Qiao, R.; Gao, M. Macromol. Rapid. Commun. 2010, 31, 1805.
10.1002/marc.201000293
CAS PubMed Web of Science® Google Scholar
19 Zhang, Q.; Xie, G.; Zhang, H.; Zhang, J.; He, M. J. Appl. Polym. Sci. 2007, 105, 3525.
10.1002/app.26394
CAS Web of Science® Google Scholar
20 Joumaa, N.; Toussay, P.; Lansalot, M.; Elaissari, A. J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 327.
10.1002/pola.22383
CAS Web of Science® Google Scholar
21 Pich, A.; Bhattacharya, S.; Ghosh, A.; Adler, H.-J. P. Polymer 2005, 46, 4596.
10.1016/j.polymer.2005.01.017
CAS Web of Science® Google Scholar
22 Medeiros, S. F.; Santos, A. M.; Fessi, H.; Elaissari, A. J. Colloid Sci. Biotechnol. 2012, 1, 99.
10.1166/jcsb.2012.1002
CAS Google Scholar
23 Luo, Y.-D.; Dai, C.-A.; Chiu, W.-Y. J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 1014.
10.1002/pola.22444
CAS Web of Science® Google Scholar
24 Ugelstad, J.; Mórk, P. C.; Kaggerud, K. H.; Ellingsen, T.; Berge, A. Adv. Colloid. Interface Sci. 1980, 13, 101.
10.1016/0001-8686(80)87003-5
CAS Web of Science® Google Scholar
25 Zhou, X.; Ni, S.; Wang, X.; Wu, F. Curr. Nanosci. 2007, 3, 259.
10.2174/157341307781422942
CAS Web of Science® Google Scholar
26 Lan, Q.; Liu, C.; Yang, F.; Liu, S.; Xu, J.; Sun, D. J. Colloid. Interface Sci. 2007, 310, 260.
10.1016/j.jcis.2007.01.081
CAS PubMed Web of Science® Google Scholar
27 Corr, S. A.; Gun'ko, Y. K.; Tekoriute, R.; Meledandri, C. J.; Brougham, D. F. J. Phys. Chem. C 2008, 112, 13324.
10.1021/jp805519n
CAS Web of Science® Google Scholar
28 Acar, H. Y.; Garaas, R. S.; Syud, F.; Bonitatebus, P.; Kulkarni, A. M. J. Magn. Magn. Mater. 2005, 293, 1.
10.1016/j.jmmm.2005.01.035
CAS Web of Science® Google Scholar

Citing Literature

Volume129, Issue4

15 August 2013

Pages 1726-1733

Synthesis of highly loaded and well-controlled magnetic beads via emulsion polymerization

Abstract

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Synthesis of highly loaded and well-controlled magnetic beads via emulsion polymerization

Abstract

References

Citing Literature

References

Related

Information