Two-stage grafting onto polyethylene fiber by radiation-induced graft polymerization and atom transfer radical polymerization
Makoto Komatsu
Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo 162-8601, Japan
Ebara Corporation, 11-1 Haneda Asahi-cho, Ohta-ku, Tokyo 144-8510, Japan
Search for more papers by this authorTakashi Kawakami
Ebara Corporation, 11-1 Haneda Asahi-cho, Ohta-ku, Tokyo 144-8510, Japan
Search for more papers by this authorJun-Ichi Kanno
Ebara Corporation, 11-1 Haneda Asahi-cho, Ohta-ku, Tokyo 144-8510, Japan
Search for more papers by this authorCorresponding Author
Takeo Sasaki
Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo 162-8601, Japan
Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo 162-8601, Japan===Search for more papers by this authorMakoto Komatsu
Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo 162-8601, Japan
Ebara Corporation, 11-1 Haneda Asahi-cho, Ohta-ku, Tokyo 144-8510, Japan
Search for more papers by this authorTakashi Kawakami
Ebara Corporation, 11-1 Haneda Asahi-cho, Ohta-ku, Tokyo 144-8510, Japan
Search for more papers by this authorJun-Ichi Kanno
Ebara Corporation, 11-1 Haneda Asahi-cho, Ohta-ku, Tokyo 144-8510, Japan
Search for more papers by this authorCorresponding Author
Takeo Sasaki
Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo 162-8601, Japan
Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo 162-8601, Japan===Search for more papers by this authorAbstract
Two-stage graft polymerization onto polyethylene (PE) fiber was demonstrated. The graft side chain was formed by radiation-induced graft polymerization. A PE fiber was irradiated with an electron beam and immersed in a vinyl monomer solution. The terminal of the formed graft chain was halogenated using N-bromosuccinimide. The halogenated graft chain was then extended by atom transfer radical polymerization to obtain block-copolymer grafted PE fibers. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010
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