Blends of poly(L-lactic acid) with poly(ω-pentadecalactone) synthesized by enzyme-catalyzed polymerization

Corresponding Author

Koji Nakane

[email protected]

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan===Search for more papers by this author

Chiharu Tamaki,

Chiharu Tamaki

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

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Yoshihiro Hata,

Yoshihiro Hata

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

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Takashi Ogihara,

Takashi Ogihara

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

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Nobuo Ogata,

Nobuo Ogata

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

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Koji Nakane,

Corresponding Author

Koji Nakane

[email protected]

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan===Search for more papers by this author

Chiharu Tamaki,

Chiharu Tamaki

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

Search for more papers by this author

Yoshihiro Hata,

Yoshihiro Hata

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

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Takashi Ogihara,

Takashi Ogihara

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

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Nobuo Ogata,

Nobuo Ogata

Materials Science and Engineering Course, Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan

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First published: 04 February 2008

https://doi.org/10.1002/app.27838

Citations: 6

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Abstract

Poly(ω-pentadecalactone) (PPDL) was synthesized by enzyme-catalyzed polymerization. The molecular weight of the PPDL was about 35,000. Opaque poly(L-lactic acid) (PLLA)/PPDL blend films were created by the solvent casting technique. The addition of PPDL led to PLLA crystallization. Furthermore, the addition of PPDL with PLLA increased both the Young's modulus [pure PLLA : 0.67 GPa, PLLA/PPDL (70/30 wt %) : 1.01 GPa] and the PLLA glass transition temperature. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008

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Volume108, Issue4

15 May 2008

Pages 2139-2143

Blends of poly(L-lactic acid) with poly(ω-pentadecalactone) synthesized by enzyme-catalyzed polymerization

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Blends of poly(L-lactic acid) with poly(ω-pentadecalactone) synthesized by enzyme-catalyzed polymerization

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