Effect of CsBr–MnCl₂ mixed fillers on the crystal structure and optical and electrical properties of poly(vinyl alcohol)

Poly(vinyl alcohol) (PVA) films filled with (x)CsBr(15 − x)MnCl₂, where 0.0 ≤ x ≤ 15%, were prepared by a casting technique. The crystal structure properties of the prepared films were examined by XRD, DTA, and FTIR. A correlation between XRD, DTA, and FTIR of the filled polymer was discussed. Optical absorption measurements revealed two optical band gaps (E_g1 and E_g2). The electrical properties were studied using dc electrical conductivity. The filling level (FL) dependency of E_g1 and E_g2, thermal activation energy (ΔE), and hopping distance (R₀) are given to illustrate the behavior of the filled polymers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2178–2186, 2004