Volume 37, Issue 11 pp. 3105-3117

Article

Full Access

Polyethylene adhesion: Pretreatment with potassium permanganate

Ricardo Aurélio Da Costa,

Ricardo Aurélio Da Costa

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Search for more papers by this author

Maria Do Carmo Gonçalves,

Maria Do Carmo Gonçalves

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Search for more papers by this author

Marcelo Ganzarolli De Oliveira,

Marcelo Ganzarolli De Oliveira

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Search for more papers by this author

Adley Forti Rubira,

Adley Forti Rubira

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Universidade Estadual de Maringá, Maringá PR, Brazil.

Search for more papers by this author

Fernando Galembeck,

Corresponding Author

Fernando Galembeck

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil===Search for more papers by this author

Ricardo Aurélio Da Costa,

Ricardo Aurélio Da Costa

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Search for more papers by this author

Maria Do Carmo Gonçalves,

Maria Do Carmo Gonçalves

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Search for more papers by this author

Marcelo Ganzarolli De Oliveira,

Marcelo Ganzarolli De Oliveira

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Search for more papers by this author

Adley Forti Rubira,

Adley Forti Rubira

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Universidade Estadual de Maringá, Maringá PR, Brazil.

Search for more papers by this author

Fernando Galembeck,

Corresponding Author

Fernando Galembeck

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil

Instituto de Química, Universidade Estadual de Campinas, 13081 Campinas SP, Brazil===Search for more papers by this author

First published: 5 June 1989

https://doi.org/10.1002/app.1989.070371104

Citations: 5

About

PDF

Tools

Share a link

Email
Wechat
Bluesky

Abstract

Two major events occur in the modification of polyethylene (PE) surfaces by treatment with acidic KMnO₄ solutions: The polymer surface is coated with a porous MnO₂ layer and corroded, by oxidation. In both cases the resulting surfaces may be bonded with epoxy; the average peeling force for LDPE/epoxy/LDPE adhesive joints thus obtained may reach > 1.6 kN m⁻¹ and is limited by adherend cohesive failure. Modified LDPE surfaces and disassembled joints were examined by transmission and ATR-IR spectrophotometry, to show that corroded, nonwettable LDPE contains appreciable amounts of polar groups, reactive towards epoxy amine components.

References

1 S. Yamakawa, J. Appl. Polym. Sci., 20, 3057 (1984).
10.1002/app.1976.070201112
Web of Science® Google Scholar
2 K. Rossmann, J. Polym. Sci., 19, 141 (1956).
10.1002/pol.1956.120199114
CAS Web of Science® Google Scholar
3 R. H. Hansen and H. Schonhorn, J. Polym. Sci. B, 4, 203 (1966).
10.1002/pol.1966.110040309
CAS Web of Science® Google Scholar
4 N. A. de Bruyne, Nature, 10, 262 (1957).
10.1038/180262a0
Google Scholar
5 J. R. Rasmussem, E. R. Stedronsky, and G. M. Whitesides, J. Am. Chem. Soc., 99, 4736 (1977).
10.1021/ja00456a035
Web of Science® Google Scholar
6 J. C. Ericksson, C. G. Goländer, A. Baszkin, and L. Ter-Minassian Saraga, 100, 381 (1984).
Google Scholar
7 H. R. S. Farley, R. H. Reamey, T. J. McCarthy, J. Deutch, and G. M. Whitesides, Langmuir, 1, 725 (1985).
10.1021/la00066a016
Web of Science® Google Scholar
8 A. F. Rubira and F. Galembeck, in Proceedings of the IV Japan-Brazil Symposium on Science and Technology, Rio de Janeiro, Brazil, 1984, p. 341.
Google Scholar
9 F. Galembeck, S. E. Galembeck, H. Vargas, C. A. Ribeiro, L. C. M. Miranda, and C. C. Ghizoni, in Surface Contamination, K. L. Mittal, Ed., Plenum, New York, 1979, Vol. 1, p. 57.
10.1007/978-1-4684-3506-1_3
Google Scholar
10 A. F. Rubira, A. C. da Costa, and F. Galembeck, Colloids Surfaces, 15, 63 (1985).
10.1016/0166-6622(85)80056-1
CAS Web of Science® Google Scholar
11 Standard method of test for peel resistance of adhesives (T-Peel Test), ASTM, 1876-72.
Google Scholar
12 A. Kozawa, J. Electrochem. Soc., 106, 552 (1959).
10.1149/1.2427436
CAS Web of Science® Google Scholar
13 A. Guinier and G. Fournet, Small Angle Scattering of X-Rays, Chapman and Hall, London, 1955.
Google Scholar
14 A. W. Adamson, Physical Chemistry of Surfaces, 4th ed., Wiley, New York, 1983.
Google Scholar
15 A. F. Rubira, M. G. de Oliveira, N. F. Leite, C. C. Cesar, H. Vargas, and F. Galembeck, in Proceedings of the 4th International Meeting on Polymer Science and Technology, La Plata, Argentina, 1985, p. 373.
Google Scholar
16 J. W. Murray, J. Colloid Interf. Sci., 46(3), 357 (1974).
10.1016/0021-9797(74)90045-9
CAS Web of Science® Google Scholar
17 D. R. Gagnon and T. J. McCarthy, J. Appl. Polym. Sci., 29, 4335 (1984).
10.1002/app.1984.070291262
CAS Web of Science® Google Scholar
18 M. A. Baltanäs, A. B. Stiles, and J. B. Katzer, J. Catal., 88, 362 (1984).
10.1016/0021-9517(84)90013-7
CAS Web of Science® Google Scholar
19 B. C. Mehrota and R. Bohra, Metal Carboxilates, Academic, London, 1983.
Google Scholar
20 D. A. Saucy, S. J. Simko, and R. W. Sinton, Anal. Chem., 57, 871 (1985).
10.1021/ac00281a021
CAS Web of Science® Google Scholar
21 J. A. Gardella Jr., G. L. Grohe, W. L. Hopson, and E. M. Eyring, Anal. Chem., 56, 1169 (1984).
10.1021/ac00271a026
CAS PubMed Web of Science® Google Scholar
22 A. Baszkin and L. Ter-Minassian-Saraga, Polymer, 15, 759 (1974).
10.1016/0032-3861(74)90030-5
CAS Web of Science® Google Scholar
23 A. Bazkin and L. Ter-Minassian-Saraga, Polymer, 19, 1083 (1978).
10.1016/0032-3861(78)90152-0
Web of Science® Google Scholar
24 A. Yerger and G. M. Barrow, J. Am. Chem. Soc., 77, 4474 (1955).
10.1021/ja01622a009
CAS Web of Science® Google Scholar
25 M. Avram and G. H. D. Mateescu, Infrared Spectroscopy—Applications in Organic Chemistry, Wiley-Interscience, New York, 1972.
Google Scholar
26 R. M. Silverstein, G. C. Bassler, Spectrometric Identification of Organic Compounds, 2nd ed., Wiley, New York, 1962.
10.1021/ed039p546
Google Scholar
27 N. J. De Lollis, in Adhesives, Adherends, Adhesion, R. E. Krieger, Ed., Plenum, New York, 1980, Chap. 2.
Google Scholar
28 R. H. Olley and D. C. Basset, Polymer, 23, 1707 (1982).
10.1016/0032-3861(82)90110-0
CAS Web of Science® Google Scholar
29 S. Yamakawa and F. Yamamoto, J. Appl. Polym. Sci., 25, 41 (1980).
10.1002/app.1980.070250104
CAS Web of Science® Google Scholar

Citing Literature

Volume37, Issue11

5 June 1989

Pages 3105-3117

Polyethylene adhesion: Pretreatment with potassium permanganate

Abstract

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Polyethylene adhesion: Pretreatment with potassium permanganate

Abstract

References

Citing Literature

References

Related

Information