Volume 32, Issue 6 pp. 5557-5565
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On the mathematical modeling of mechanochemical degradation of acrylonitrile–α-methyl styrene–vinyl acetate terpolymer in conditions simulating the wet-spinning

Cleopatra Vasiliu Oprea

Cleopatra Vasiliu Oprea

Department of Organic and Macromolecular Chemistry, Polytechnic Institute of Jassy, 23 August Street, No 11A, 6600 Jassy, Romania

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Marcel Popa

Marcel Popa

Department of Organic and Macromolecular Chemistry, Polytechnic Institute of Jassy, 23 August Street, No 11A, 6600 Jassy, Romania

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Simion Petrovan

Simion Petrovan

Department of Organic and Macromolecular Chemistry, Polytechnic Institute of Jassy, 23 August Street, No 11A, 6600 Jassy, Romania

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First published: 5 November 1986
Citations: 3

Abstract

This article aims to carry out mathematical modeling of the mechanochemical degradation process of acrylonitrile–α-methyl styrene–vinyl acetate ternary copolymer in conditions that simulate its wet-spinning from dimethyl formamide solution. The influence of some factors on the mechanochemical degradation process is studied. Based on a great number of experiments a regression equation is determined, which correlates the intrinsic viscosity of the copolymer solution with the mechanical process variables (the length and length/diameter ratio, solution concentration, and pressure).

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