Polymérisation des méthacrylates d'ethers glycériques par le peroxyde de benzoyle: Accélération de la polymérisation par les sulfinates d'amines tertiaries

The kinetic study of the radical polymerization of phenyl glyceric ether methacrylate, taken as model of the corresponding derivative of bisphenol A, initiated by the system benzoyl peroxide/dimethyl p-toluidine p-toluene sulfinic acid salt, was performed. The effect of hydroxylic groups of the monomer on the polymerizability was established. The system used as initiator allows rapid polymerization of the monomer in presence of stabilizers.