Volume 22, Issue 1 pp. 289-297
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The structure of hydrous Zr(IV) oxide–polyacrylate membranes: Poly(acrylic acid) deposition

G. B. Tanny

G. B. Tanny

Department of Plastics Research, The Weizmann Institute of Science, Rehovot, Israel

The Chemistry Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830

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James S. Johnson Jr.

James S. Johnson Jr.

Department of Plastics Research, The Weizmann Institute of Science, Rehovot, Israel

The Chemistry Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830

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First published: January 1978
Citations: 22

Research sponsored by the Energy Research and Development Administration under contract with Union Carbide Corporation.

Abstract

The formation of hydrous Zr(IV) oxide–polyacrylate dynamic membranes was studied by the dependence of water flux decline and steady-state water flux on the concentration of poly(acrylic acid) in the feed. Analysis of the results indicates that the poly(acrylic acid) enters the pores of the hydrous Zr(IV) oxide layer, rather than forming a second layer. This configuration was consistent with scanning electron micrographs of the surface.

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