Volume 9, Issue 2 pp. 411-419
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Preparation and chelating properties of 8-hydroxy-quinoline—formaldehyde polymers

R. C. Degeiso

R. C. Degeiso

Department, Experimental Station Laboratory, E. I. du Pont de Nemours and Company, Inc., Wilmington, Delaware

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L. G. Donaruma

L. G. Donaruma

Department, Experimental Station Laboratory, E. I. du Pont de Nemours and Company, Inc., Wilmington, Delaware

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E. A. Tomic

E. A. Tomic

Department, Experimental Station Laboratory, E. I. du Pont de Nemours and Company, Inc., Wilmington, Delaware

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First published: February 1965
Citations: 51

Abstract

Condensation of 8-hydroxyquinoline with formaldehyde in acid solution yielded a polymer of molecular weight ∽3300. Modification of this polymer with resorcinol resulted in improved physical properties of this material. 8-Hydroxyquinoline-formaldehyde polymers can be used as selective chelating ion-exchange rains which permit separation of various cations. The polymeric metd chelates are thermally less stable than the unchelated polymer.

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