Volume 80, Issue 11 pp. 2024-2030

Nitroxide-mediated homopolymerization and copolymerization of 2-vinylpyridine with styrene

Corresponding Author

J. Lokaj

Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic

Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic===Search for more papers by this author

P. Holler,

P. Holler

Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic

Search for more papers by this author

J. Lokaj,

Corresponding Author

J. Lokaj

Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic

Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic===Search for more papers by this author

P. Holler,

P. Holler

Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic

Search for more papers by this author

First published: 20 March 2001

https://doi.org/10.1002/app.1300

Citations: 18

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Abstract

Homopolymerization and copolymerization of 2-vinylpyridine (2VP) with styrene (S) at 125°C in the presence of 2,2,6,6-tetramethyl piperidin-1-yloxyl (TEMPO) radicals have been studied. The homopolymerization was carried out with 2,2′-azobis(isobutyronitrile) (AIBN) as a thermal initiator or without AIBN in the initial reaction mixture. In the copolymerization initiated with AIBN, the molar fraction of 2VP in the feed, F_2VP, varied in the range of 0.1–0.9; F_2VP = 0.65 was found to be the azeotropic composition. The linear semilogarithmic time–conversion plots demonstrated a pseudoliving nature of the polymerizations under study. The molecular weight–conversion dependences indicated the participation of side reactions, diminishing the number of TEMPO-terminated polymer chains. The synthesized homopolymers and copolymers were characterized using size-exclusion chromatography (SEC), nitrogen analysis, and NMR spectroscopy. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 2024–2030, 2001

REFERENCES

1 Otsu, T.; Yoshida, M. Makromol Chem Rapid Commun 1982, 3, 127.
10.1002/marc.1982.030030208
CAS Web of Science® Google Scholar
2 Otsu, T.; Yoshida, M.; Tazaki, T. Makromol Chem Rapid Commun 1982, 3, 133.
10.1002/marc.1982.030030209
CAS Web of Science® Google Scholar
3 Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Macromolecules 1993, 26, 2987.
10.1021/ma00063a054
CAS Web of Science® Google Scholar
4 Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym Sci 1994, 2, 66.
Google Scholar
5 Wang, J. S.; Matyjaszewski, K. J Am Chem Soc 1995, 117, 5614.
10.1021/ja00125a035
CAS Web of Science® Google Scholar
6 Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721.
10.1021/ma00109a056
CAS Web of Science® Google Scholar
7 Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901.
10.1021/ma00127a042
CAS Web of Science® Google Scholar
8 Percec, V.; Barboiu, B. Macromolecules 1995, 28, 7970.
10.1021/ma00127a057
CAS Web of Science® Google Scholar
9 Chiefari, J.; Chong, Y. K.; Ercole, F.; Moad, C. L.; Moad, G.; Rizzardo, E.; Thang, S. H. Macromolecules 1998, 31, 5559.
10.1021/ma9804951
CAS Web of Science® Google Scholar
10 Gaynor, S.; Greszta, D.; Mardare, D.; Teodorescu, M.; Matyjaszewski, K. J Macromol Sci Pure Appl Chem 1994, 31, 1561.
10.1080/10601329408545868
CAS Web of Science® Google Scholar
11 Veregin, R. P. N.; Georges, M. K.; Hamer, G. K.; Kazmaier, P. M. Macromolecules 1995, 28, 4391.
10.1021/ma00117a006
CAS Web of Science® Google Scholar
12 Keoskerian, B.; Georges, M. K.; Boies-Boissier, D. Macromolecules 1995, 28, 6381.
10.1021/ma00122a058
CAS Web of Science® Google Scholar
13 Hawker, C. J.; Hedrick, J. L. Macromolecules 1995, 28, 2993.
10.1021/ma00112a056
CAS Web of Science® Google Scholar
14 Aoshima, K.; Ohumura, H.; Mouya, Y.; Suzuki, N.; Oshiba, Y. Polymer 1991, 32, 19.
10.1016/0032-3861(91)90556-X
CAS Web of Science® Google Scholar
15 Hawker, C. J.; Elce, E.; Dao, J.; Volksen, W.; Russell, T. P.; Barclay, G. G. Macromolecules 1996, 29, 2686.
10.1021/ma9515137
CAS Web of Science® Google Scholar
16 Hawker, C. J.; Barclay, G. G.; Orellana, A.; Dao, J.; Dewonport, W. Macromolecules 1996, 29, 5245.
10.1021/ma951905d
CAS Web of Science® Google Scholar
17 Fukuda, T.; Terauchi, T.; Goto, A.; Tsujii, Y.; Miya- moto, T.; Shimizu, Y. Macromolecules 1996, 29, 3050.
10.1021/ma951792y
CAS Web of Science® Google Scholar
18 Kazmaier, P. M.; Daimon, K.; Georges, M. K.; Hamer, G. K.; Veregin, R. P. N. Macromolecules 1997, 30, 2228.
10.1021/ma961101d
CAS Web of Science® Google Scholar
19 Devonport, W.; Michalak, L.; Malmström, E.; Mate, M.; Kurdi, B.; Hawker, C. J.; Barclay, G. G.; Sinta, R. Macromolecules 1997, 30, 1929.
10.1021/ma9615866
CAS Web of Science® Google Scholar
20 Lokaj, J.; Vlček, P.; Kříž, J. Macromolecules 1997, 30, 7644.
10.1021/ma971192u
CAS Web of Science® Google Scholar
21 Ohno, K.; Tsujii, Y.; Miyamoto, T.; Fukuda, T.; Goto, M.; Kobayashi, K.; Akaike, T. Macromolecules 1998, 31, 1064.
10.1021/ma971329g
CAS Web of Science® Google Scholar
22 Ohno, K.; Ejaz, M.; Fukuda, T.; Miyamoto, T.; Shimizu, Y. Macromol Chem Phys 1998, 199, 291.
10.1002/(SICI)1521-3935(19980201)199:2<291::AID-MACP291>3.0.CO;2-D
CAS Web of Science® Google Scholar
23 Benoit, D.; Chaplinski, V.; Braslau, R.; Hawker, C. J. J Am Chem Soc 1999, 121, 3904.
10.1021/ja984013c
CAS Web of Science® Google Scholar
24 Gabatson, L. I.; Furlong, S. A.; Jackson, R. A.; Armes, S. P. Polymer 1999, 40, 4505.
10.1016/S0032-3861(98)00689-2
Web of Science® Google Scholar
25 Bohrisch, J.; Wendler, U.; Jaeger, W. Macromol Rapid Commun 1997, 18, 975.
10.1002/marc.1997.030181104
CAS Web of Science® Google Scholar
26 Wendler, U.; Bohrisch, J.; Jaeger, W.; Rother, G.; Dautzenberg, H. Macromol Rapid Commun 1998, 19, 185.
10.1002/(SICI)1521-3927(19980401)19:4<185::AID-MARC185>3.0.CO;2-G
CAS Web of Science® Google Scholar
27 Goto, A.; Fukuda, T. Macromolecules 1999, 32, 618.
10.1021/ma981403a
CAS Web of Science® Google Scholar
28 Burgiere, C.; Dourges, M.-A.; Charleux, B.; Vairon, J.-P. Macromolecules 1999, 32, 3883.
10.1021/ma982037y
Web of Science® Google Scholar
29 Fischer, A.; Brembilla, A.; Lochon, P. Macromolecules 1999, 32, 6069.
10.1021/ma990116j
CAS Web of Science® Google Scholar
30 Chong, Y. K.; Ercole, F.; Moad, G.; Rizzardo, E.; Thang, S. H.; Anderson, A. G. Macromolecules 1999, 32, 6895.
10.1021/ma9904868
CAS Web of Science® Google Scholar
31 Khan, I. M. In Encyclopedia of Polymer Science and Engineering; Wiley: New York, 1989, 17, 567.
Google Scholar
32 Tamikado, T. J Polym Sci 1960, 43, 489.
10.1002/pol.1960.1204314218
CAS Web of Science® Google Scholar
33 J. Brandrup; E. H. Immergut; E. A. Grulke; Eds. Polymer Handbook; Wiley: New York, 1999, 4th ed.
Google Scholar

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Volume80, Issue11

13 June 2001

Pages 2024-2030

Nitroxide-mediated homopolymerization and copolymerization of 2-vinylpyridine with styrene

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Nitroxide-mediated homopolymerization and copolymerization of 2-vinylpyridine with styrene

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