Volume 32, Issue 6 e4356
FULL PAPER

Porous Si/TiO2 nanowire photoanode for photoelectric catalysis under simulated solar light irradiation

Zhangxiaoxiong Chen

Zhangxiaoxiong Chen

School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun, 130012 People's Republic of China

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Jikai Yang

Corresponding Author

Jikai Yang

School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun, 130012 People's Republic of China

Correspondence

Jikai Yang, School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun 130012, China.

Email: [email protected]

Xiaotian Yang, Jilin Provincial Key Laboratory of Architectural Electricity and Comprehensive Energy Saving, Jilin Jianzhu University, Changchun 130118, China.

Email: [email protected]

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Xiaotian Yang

Corresponding Author

Xiaotian Yang

Jilin Provincial Key Laboratory of Architectural Electricity and Comprehensive Energy Saving, School of Electrical and Electronic Information Engineering, Jilin Jianzhu University, Changchun, 130118 People's Republic of China

State Key Laboratory of Synthesis and Preparative Chemistry, Jilin University, 2699 Qianjin Road, Changchun, 130012 People's Republic of China

Correspondence

Jikai Yang, School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun 130012, China.

Email: [email protected]

Xiaotian Yang, Jilin Provincial Key Laboratory of Architectural Electricity and Comprehensive Energy Saving, Jilin Jianzhu University, Changchun 130118, China.

Email: [email protected]

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Yiming Zhao

Yiming Zhao

School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun, 130012 People's Republic of China

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Jiaqi Kang

Jiaqi Kang

School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun, 130012 People's Republic of China

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Fuyu Yang

Fuyu Yang

School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun, 130012 People's Republic of China

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Yufei Zhang

Yufei Zhang

School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun, 130012 People's Republic of China

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Ming Cheng

Ming Cheng

School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun, 130012 People's Republic of China

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Guozheng Wang

Guozheng Wang

School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun, 130012 People's Republic of China

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Qingduo Duanmu

Qingduo Duanmu

School of Science, Changchun University of Science and Technology, 7089 Weixing Road, Changchun, 130012 People's Republic of China

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First published: 20 April 2018
Citations: 12

Abstract

Porous Si/TiO2 nanowire photoanodes were prepared by a combination of hydrothermal synthesis and metal-assisted chemical etching. Characterization of samples was conducted using scanning electron microscopy and X-ray diffraction, the results showing that a porous Si/TiO2 heterojunction structure was synthesized. Diffuse reflection spectra show that the porous Si/TiO2 nanowire photoanodes have a strong absorption. Photocurrent measurement shows that the photocurrent of the porous Si/TiO2 nanowire photoanodes at 6 h is higher than that of others in the measuring region. The photoelectric catalysis (PEC) activities of porous Si/TiO2 nanowire photoanodes were evaluated in degradation experiments of methylene blue under simulated solar light irradiation, and the sample at 6 h shows the highest PEC activity. Meanwhile, the PEC activity of the porous Si/TiO2 nanowire photoanode is higher than that of the single direct photocatalysis process or electric catalysis. The mechanism of the PEC of the porous Si/TiO2 nanowire photoanodes has been explained.

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