The Transfer Dehydrogenation Method Enables a Family of High Crystalline Benzimidazole-linked Cu (II)-phthalocyanine-based Covalent Organic Frameworks Films
Qingsong Zhang
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contributed equally to this manuscript.
Contribution: Data curation (lead), Formal analysis (lead), Writing - original draft (lead)
Search for more papers by this authorZhiheng Zhu
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contributed equally to this manuscript.
Contribution: Data curation (equal), Formal analysis (equal), Writing - original draft (equal)
Search for more papers by this authorLiping Liu
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Department of Chemistry, Tsinghua University, Beijing, Beijing, 100084 P. R. China
Contributed equally to this manuscript.
Contribution: Data curation (equal), Formal analysis (equal), Writing - original draft (equal)
Search for more papers by this authorHaojie Huang
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorXianjie Chen
State Key Laboratory of Environment-friendly Energy Materials, School of Materials and Chemistry, Southwest University of Science and Technology, Mianyang, 621010 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorYangshuang Bian
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorMingchao Shao
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorXiaofang Wei
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorChengyu Wang
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorDong Wang
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorJichen Dong
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorCorresponding Author
Yunlong Guo
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Conceptualization (equal), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Yongfa Zhu
Department of Chemistry, Tsinghua University, Beijing, Beijing, 100084 P. R. China
Contribution: Conceptualization (equal), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Yunqi Liu
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorQingsong Zhang
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contributed equally to this manuscript.
Contribution: Data curation (lead), Formal analysis (lead), Writing - original draft (lead)
Search for more papers by this authorZhiheng Zhu
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contributed equally to this manuscript.
Contribution: Data curation (equal), Formal analysis (equal), Writing - original draft (equal)
Search for more papers by this authorLiping Liu
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Department of Chemistry, Tsinghua University, Beijing, Beijing, 100084 P. R. China
Contributed equally to this manuscript.
Contribution: Data curation (equal), Formal analysis (equal), Writing - original draft (equal)
Search for more papers by this authorHaojie Huang
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorXianjie Chen
State Key Laboratory of Environment-friendly Energy Materials, School of Materials and Chemistry, Southwest University of Science and Technology, Mianyang, 621010 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorYangshuang Bian
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorMingchao Shao
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorXiaofang Wei
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorChengyu Wang
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorDong Wang
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorJichen Dong
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Data curation (supporting), Writing - original draft (supporting)
Search for more papers by this authorCorresponding Author
Yunlong Guo
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Contribution: Conceptualization (equal), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Yongfa Zhu
Department of Chemistry, Tsinghua University, Beijing, Beijing, 100084 P. R. China
Contribution: Conceptualization (equal), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Yunqi Liu
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorGraphical Abstract
In this work, we proposed a transfer dehydrogenation method to prepare a novel series of imidazole-linked phthalocyanine Cu (II)-based covalent organic frameworks (BICuPc-COFs) films and powders. The high crystalline BICuPc-COFs films that possess intrinsic conductivity (0.022–0.218 S/m) were fabricated into synaptic devices, which have small source-drain voltage (VDS=1 V) and response light from visible to near-infrared.
Abstract
Heterocycle-linked phthalocyanine-based COFs with close-packed π–π conjugated structures are a kind of material with intrinsic electrical conductivity, and they are considered to be candidates for photoelectrical devices. Previous studies have revealed their applications for energy storage, gas sensors, and field-effect transistors. However, their potential application in photodetector is still not fully studied. The main difficulty is preparing high-quality films. In our study, we found that our newly designed benzimidazole-linked Cu (II)-phthalocyanine-based COFs (BICuPc-COFs) film can hardly formed with a regular aerobic oxidation method. Therefore, we developed a transfer dehydrogenation method with N-benzylideneaniline (BA) as a mild reagent. With this in hand, we successfully prepared a family of high crystalline BICuPc-COFs powders and films. Furthermore, both of these new BICuPc-COFs films showed high electrical conductivity (0.022–0.218 S/m), higher than most of the reported COFs materials. Due to the broad absorption and high conductivity of BICuPc-COFs, synaptic devices with small source-drain voltage (VDS=1 V) were fabricated with response light from visible to near-infrared. Based on these findings, we expect this study will provide a new perspective for the application of conducting heterocycle-linked COFs in synaptic devices.
Conflict of interests
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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