Volume 62, Issue 29 e202306854
Cover Picture
Free Access

Cover Picture: Cyclotetrabenzil Derivatives for Electrochemical Lithium-Ion Storage (Angew. Chem. Int. Ed. 29/2023)

Jianing Meng

Jianing Meng

Department of Chemistry, University of Houston, 3585 Cullen Blvd., Houston, TX-77204-5003 USA

These authors contributed equally to this work.

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Dr. Alexandra Robles

Dr. Alexandra Robles

Department of Chemistry, University of Houston, 3585 Cullen Blvd., Houston, TX-77204-5003 USA

These authors contributed equally to this work.

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Dr. Said Jalife

Dr. Said Jalife

Department of Chemistry, University of Houston, 3585 Cullen Blvd., Houston, TX-77204-5003 USA

These authors contributed equally to this work.

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Wen Ren

Wen Ren

Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX-77204-4004 USA

These authors contributed equally to this work.

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Ye Zhang

Ye Zhang

Department of Electrical and Computer Engineering and Materials Science and Engineering Program, University of Houston, Houston, TX-77204 USA

Texas Center for Superconductivity at the University of Houston, University of Houston, Houston, TX-77204 USA

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Dr. Lihong Zhao

Dr. Lihong Zhao

Department of Electrical and Computer Engineering and Materials Science and Engineering Program, University of Houston, Houston, TX-77204 USA

Texas Center for Superconductivity at the University of Houston, University of Houston, Houston, TX-77204 USA

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Dr. Yanliang Liang

Corresponding Author

Dr. Yanliang Liang

Department of Electrical and Computer Engineering and Materials Science and Engineering Program, University of Houston, Houston, TX-77204 USA

Texas Center for Superconductivity at the University of Houston, University of Houston, Houston, TX-77204 USA

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Prof. Dr. Judy I. Wu

Corresponding Author

Prof. Dr. Judy I. Wu

Department of Chemistry, University of Houston, 3585 Cullen Blvd., Houston, TX-77204-5003 USA

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Prof. Dr. Ognjen Š. Miljanić

Corresponding Author

Prof. Dr. Ognjen Š. Miljanić

Department of Chemistry, University of Houston, 3585 Cullen Blvd., Houston, TX-77204-5003 USA

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Prof. Dr. Yan Yao

Corresponding Author

Prof. Dr. Yan Yao

Department of Electrical and Computer Engineering and Materials Science and Engineering Program, University of Houston, Houston, TX-77204 USA

Texas Center for Superconductivity at the University of Houston, University of Houston, Houston, TX-77204 USA

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First published: 22 June 2023

Graphical Abstract

Organic electrode materials could break the dependency of lithium-ion batteries on minerals that are scarce and mined in conflict zones. In their Communication (e202300892), Yanliang Liang, Judy I. Wu, Ognjen Š. Miljanić, Yan Yao et al. report a naphthalene-based cyclotetrabenzil macrocycle as a promising organic electrode candidate. Its eight redox-active groups bring about a high specific capacity of 279 mAh g−1, while the low solubility—a consequence of the shape-persistent structure—results in stable cycling performance. Cover art: Ella Maru Studio.

Organic electrode materials could break the dependency of lithium-ion batteries on minerals that are scarce and mined in conflict zones. In their Communication (e202300892), Yanliang Liang, Judy I. Wu, Ognjen Š. Miljanić, Yan Yao et al. report a naphthalene-based cyclotetrabenzil macrocycle as a promising organic electrode candidate. Its eight redox-active groups bring about a high specific capacity of 279 mAh g−1, while the low solubility—a consequence of the shape-persistent structure—results in stable cycling performance. Cover art: Ella Maru Studio.

Chalcogen Bond

Chalcogen bonding can play a significant role in designing complex bioinspired structures. In their Research Article (e202304202), Gebhard Haberhauer et al. employ two different types of this interaction to construct single and double helices from planar benzotellurazole amides.

Polymers

In their Communication (e202305747), Tamaki Nakano et al. report the inclusion of aromatic small molecules in the interior space of optically active poly(fluorenevinylene) derivatives. The small molecules exhibit circular dichroism and efficient circularly polarized luminescence.

CO2 Valorization

In their Research Article (e202302096), Xu Xiang, Jing He and co-workers unveil that the increased *H coverage on a layered Cu-based catalyst favors hydrogenation of *HCCOH to *HCCHOH and prioritizes the ethanol pathway, enabling highly efficient and durable production of ethanol.

Metal–Organic Frameworks

Myoung Soo Lah et al. demonstrate in their Research Article (e202302376) superprotonic conductivity, utilizing metal–organic frameworks embedded with a moderately acidic guest, sulfamic acid.

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