Engineering Supramolecular Binding Sites in a Chemically Stable Metal-Organic Framework for Simultaneous High C2H2 Storage and Separation
Kai Shao
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
These authors contributed equally to this work.
Search for more papers by this authorProf. Hui-Min Wen
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014 China
These authors contributed equally to this work.
Search for more papers by this authorCong-Cong Liang
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorXiaoyan Xiao
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorXiao-Wen Gu
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Banglin Chen
Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249-0698 USA
Search for more papers by this authorProf. Guodong Qian
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Bin Li
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorKai Shao
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
These authors contributed equally to this work.
Search for more papers by this authorProf. Hui-Min Wen
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014 China
These authors contributed equally to this work.
Search for more papers by this authorCong-Cong Liang
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorXiaoyan Xiao
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorXiao-Wen Gu
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Banglin Chen
Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249-0698 USA
Search for more papers by this authorProf. Guodong Qian
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Bin Li
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorGraphical Abstract
We developed a novel strategy by engineering abundant supramolecular binding sites into a chemically stable HKUST-1-like MOF (ZJU-50a) to achieve simultaneously high C2H2 storage and selectivity, breaking the trade-off between adsorption capacity and selectivity for C2H2/CO2 separation.
Abstract
Developing porous materials to overcome the trade-off between adsorption capacity and selectivity for C2H2/CO2 separation remains a challenge. Herein, we report a stable HKUST-1-like MOF (ZJU-50a), featuring large cages decorated with high density of supramolecular binding sites to achieve both high C2H2 storage and selectivity. ZJU-50a exhibits one of the highest C2H2 storage capacity (192 cm3 g−1) and concurrently high C2H2/CO2 selectivity (12) at 298 K and 1 bar. Single-crystal X-ray diffraction studies on gas-loaded ZJU-50a crystal unveil that the incorporated supramolecular binding sites can selectively take up C2H2 molecule but not CO2 to result in both high C2H2 storage and selectivity. Breakthrough experiments validated its separation performance for C2H2/CO2 mixtures, providing a high C2H2 recovery capacity of 84.2 L kg−1 with 99.5 % purity. This study suggests a novel strategy of engineering supramolecular binding sites into MOFs to overcome the trade-off for this separation.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
Supporting Information
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| Filename | Description |
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| anie202211523-sup-0001-misc_information.pdf5.5 MB | Supporting Information |
| anie202211523-sup-0001-ZJU-50.cif455.1 KB | Supporting Information |
| anie202211523-sup-0001-ZJU-50_C2H2.cif1.6 MB | Supporting Information |
| anie202211523-sup-0001-ZJU-50_CO2.cif347.2 KB | Supporting Information |
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