Heterometallic Actinide-Containing Photoresponsive Metal-Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Corey R. Martin
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorGabrielle A. Leith
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorDr. Preecha Kittikhunnatham
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorKyoung Chul Park
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorDr. Otega A. Ejegbavwo
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorAbhijai Mathur
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorCameron R. Callahan
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorShelby L. Desmond
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorMyles R. Keener
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorFiaz Ahmed
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorDr. Shubham Pandey
Department of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, CO, 80401 USA
Search for more papers by this authorDr. Mark D. Smith
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorProf. Dr. Simon R. Phillpot
Department of Materials Science and Engineering, University of Florida, Gainesville, FL, 32611 USA
Search for more papers by this authorProf. Dr. Andrew B. Greytak
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorCorresponding Author
Prof. Dr. Natalia B. Shustova
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorCorey R. Martin
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorGabrielle A. Leith
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorDr. Preecha Kittikhunnatham
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorKyoung Chul Park
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorDr. Otega A. Ejegbavwo
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorAbhijai Mathur
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorCameron R. Callahan
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorShelby L. Desmond
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorMyles R. Keener
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorFiaz Ahmed
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorDr. Shubham Pandey
Department of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, CO, 80401 USA
Search for more papers by this authorDr. Mark D. Smith
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorProf. Dr. Simon R. Phillpot
Department of Materials Science and Engineering, University of Florida, Gainesville, FL, 32611 USA
Search for more papers by this authorProf. Dr. Andrew B. Greytak
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorCorresponding Author
Prof. Dr. Natalia B. Shustova
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208 USA
Search for more papers by this authorGraphical Abstract
The merging of heterometallic actinide-containing metal-organic frameworks and photochromic moieties allowed for dynamic tailoring of electronics properties as a function of excitation wavelength. Visualization of material photoswitchable behavior was demonstrated by construction of the first photochromic MOF-based field-effect transistor.
Abstract
Acquiring fundamental knowledge of properties of actinide-based materials is a necessary step to create new possibilities for addressing the current challenges in the nuclear energy and nuclear waste sectors. In this report, we established a photophysics–electronics correlation for actinide-containing metal-organic frameworks (An-MOFs) as a function of excitation wavelength, for the first time. A stepwise approach for dynamically modulating electronic properties was applied for the first time towards actinide-based heterometallic MOFs through integration of photochromic linkers. Optical cycling, modeling of density of states near the Fermi edge, conductivity measurements, and photoisomerization kinetics were employed to shed light on the process of tailoring optoelectronic properties of An-MOFs. Furthermore, the first photochromic MOF-based field-effect transistor, in which the field-effect response could be changed through light exposure, was constructed. As a demonstration, the change in current upon light exposure was sufficient to operate a two-LED fail-safe indicator circuit.
Conflict of interest
The authors declare no conflict of interest.
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