Nickel Metal–Organic Framework Monolayers for Photoreduction of Diluted CO2: Metal-Node-Dependent Activity and Selectivity
Bin Han
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorXinwen Ou
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorZiqi Deng
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorYao Song
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorChen Tian
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorProf. Dr. Hong Deng
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorProf. Dr. Yi-Jun Xu
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116 P. R. China
College of Chemistry, New Campus, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Zhang Lin
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorBin Han
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorXinwen Ou
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorZiqi Deng
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorYao Song
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorChen Tian
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorProf. Dr. Hong Deng
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorProf. Dr. Yi-Jun Xu
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116 P. R. China
College of Chemistry, New Campus, Fuzhou University, Fuzhou, 350116 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Zhang Lin
School of Environment and Energy, Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), South China University of Technology, Guangzhou, P. R. China
Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, South China University of Technology, Guangzhou, 510006 P. R. China
Search for more papers by this authorGraphical Abstract
Doctor node: Photocatalytic conversion of diluted CO2 with high efficiency and selectivity can be achieved on Ni metal–organic framework (MOF) monolayers (Ni MOLs). The initial adsorption of CO2 molecules is the critical step and depends on the nature of the metal node.
Abstract
Photocatalytic conversion of diluted CO2 into solar fuel is highly appealing yet still in its infancy. Herein, we demonstrate the metal-node-dependent performance for photoreduction of diluted CO2 by constructing Ni metal–organic framework (MOF) monolayers (Ni MOLs). In diluted CO2 (10 %), Ni MOLs exhibit a highest apparent quantum yield of 1.96 % with a CO selectivity of 96.8 %, which not only exceeds reported systems in diluted CO2 but also is superior to most catalysts in pure CO2. Whereas isostructural Co MOLs is almost inactive in diluted CO2, indicating the performance is dependent on the metal nodes. Experimental and theoretical investigations show that strong CO2 binding affinity of Ni MOLs is the crucial factor, which stabilizes the Ni-CO2 adducts and facilitates CO2-to-CO conversion.
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