Volume 57, Issue 14 p. 3522
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Inside Cover: Directing Aluminum Atoms into Energetically Favorable Tetrahedral Sites in a Zeolite Framework by Using Organic Structure-Directing Agents (Angew. Chem. Int. Ed. 14/2018)

Koki Muraoka

Koki Muraoka

Department of Chemical System Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656 Japan

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Prof. Watcharop Chaikittisilp

Corresponding Author

Prof. Watcharop Chaikittisilp

Department of Chemical System Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656 Japan

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Yutaka Yanaba

Yutaka Yanaba

Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505 Japan

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Prof. Takeshi Yoshikawa

Prof. Takeshi Yoshikawa

Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505 Japan

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Prof. Tatsuya Okubo

Corresponding Author

Prof. Tatsuya Okubo

Department of Chemical System Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656 Japan

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First published: 27 February 2018

Graphical Abstract

Cationic molecules in the space of anionic frameworks are known to guide the crystallization of zeolites. In addition, they have been thought to be able to control the location of aluminum, which correlates with the active sites in zeolites. In their Communication on page 3742 ff. W. Chaikittisilp, T. Okubo et al. show evidence for the ability of these molecules to direct the Al positions through energetic preferences, offering rational guidelines for the designed synthesis of zeolites with desired Al sites.

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