Review
Single-Atom Electrocatalysts
Dr. Chengzhou Zhu,
Shaofang Fu,
Qiurong Shi,
Dr. Dan Du,
Prof. Yuehe Lin,
Dr. Chengzhou Zhu
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Search for more papers by this authorShaofang Fu
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Search for more papers by this authorQiurong Shi
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Search for more papers by this authorDr. Dan Du
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Yuehe Lin
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Search for more papers by this authorDr. Chengzhou Zhu,
Shaofang Fu,
Qiurong Shi,
Dr. Dan Du,
Prof. Yuehe Lin,
Dr. Chengzhou Zhu
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Search for more papers by this authorShaofang Fu
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Search for more papers by this authorQiurong Shi
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Search for more papers by this authorDr. Dan Du
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Yuehe Lin
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA, 99164 USA
Search for more papers by this authorGraphical Abstract
When less is more: Single-atom electrocatalysts are characterized by high catalytic activity, selectivity, and maximum metal utilization. They hold great promise in various electrochemical applications, such as the oxygen reduction reaction, the hydrogen evolution reaction, and hydrocarbon conversion reactions for fuel cells.
Abstract
Recent years have witnessed a dramatic increase in the production of sustainable and renewable energy. However, the electrochemical performances of the various systems are limited, and there is an intensive search for highly efficient electrocatalysts by more rational control over the size, shape, composition, and structure. Of particular interest are the studies on single-atom catalysts (SACs), which have sparked new interests in electrocatalysis because of their high catalytic activity, stability, selectivity, and 100 % atom utilization. In this Review, we introduce innovative syntheses and characterization techniques for SACs, with a focus on their electrochemical applications in the oxygen reduction/evolution reaction, hydrogen evolution reaction, and hydrocarbon conversion reactions for fuel cells (electrooxidation of methanol, ethanol, and formic acid). The electrocatalytic performance is further considered at an atomic level and the underlying mechanisms are discussed. The ultimate goal is the tailoring of single atoms for electrochemical applications.
Conflict of interest
The authors declare no conflict of interest.
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Citing Literature
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Pages 13944-13960
