“If I were not a scientist, I would be a diplomat. The most exciting thing about research is one can try many crazy ideas, and some of them turn out to be not so crazy ...” This and more about Hideki Yorimitsu can be found on page 480.
1“Ultra-rapid Synthesis of 15O-Labeled 2-Deoxy-D-glucose for Positron Emission Tomography (PET)”: H. Yorimitsu, Y. Murakami, H. Takamatsu, S. Nishimura, E. Nakamura, Angew. Chem. Int. Ed.2005, 44, 2708;
2“Gallium-Mediated Allyl Transfer from Bulky Homoallylic Alcohol to Aldehydes via Retro-allylation: Stereoselective Synthesis of Both erythro- and threo-Homoallylic Alcohols”: S. Hayashi, K. Hirano, H. Yorimitsu, K. Oshima, Org. Lett.2005, 7, 3577. (The seminal discovery that was then extended to palladium-catalyzed CC bond cleavage.)
3“Efficient Synthesis and Versatile Reactivity of Porphyrinyl Grignard Reagents”: K. Fujimoto, H. Yorimitsu, A. Osuka, Eur. J. Org. Chem.2014, 4327. (The most reactive peripherally metalated porphyrins at that time; the present champion is porphyrinyllithium.)
4“Practical, Modular, and General Synthesis of Benzofurans through Extended Pummerer Annulation/Cross-Coupling Strategy”: K. Murakami, H. Yorimitsu, A. Osuka, Angew. Chem. Int. Ed.2014, 53, 7510;
5“Palladium-Assisted ‘Aromatic Metamorphosis’ of Dibenzothiophenes into Triphenylenes”: D. Vasu, H. Yorimitsu, A. Osuka, Angew. Chem. Int. Ed.2015, 54, 7162;
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