Highly Stable, Water-Dispersible Metal-Nanoparticle-Decorated Polymer Nanocapsules and Their Catalytic Applications†
Gyeongwon Yun
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Department of Chemistry, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Zahid Hassan
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorJiyeong Lee
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Department of Chemistry, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorJeehong Kim
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Department of Chemistry, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Nam-Suk Lee
National Institute for Nanomaterials Technology (NINT), Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Nam Hoon Kim
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Kangkyun Baek
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Ilha Hwang
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorProf. Dr. Chan Gyung Park
National Institute for Nanomaterials Technology (NINT), Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Department of Material Science and Engineering, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorCorresponding Author
Prof. Dr. Kimoon Kim
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Department of Chemistry, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Division of Advanced Materials Science, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea) http://csc.ibs.re.kr/
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)Search for more papers by this authorGyeongwon Yun
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Department of Chemistry, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Zahid Hassan
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorJiyeong Lee
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Department of Chemistry, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorJeehong Kim
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Department of Chemistry, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Nam-Suk Lee
National Institute for Nanomaterials Technology (NINT), Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Nam Hoon Kim
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Kangkyun Baek
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorDr. Ilha Hwang
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorProf. Dr. Chan Gyung Park
National Institute for Nanomaterials Technology (NINT), Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Department of Material Science and Engineering, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Search for more papers by this authorCorresponding Author
Prof. Dr. Kimoon Kim
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)
Department of Chemistry, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea)
Division of Advanced Materials Science, Pohang University of Science and Technology, Pohang, 790-784 (Republic of Korea) http://csc.ibs.re.kr/
Center for Self-assembly and Complexity (CSC), Institute for Basic Science (IBS), Pohang, 790-784 (Republic of Korea)Search for more papers by this authorThis work was supported by Institute for Basic Science (IBS) [CA1403].
Graphical Abstract
Desirable tailoring: Hollow polymer nanocapsules (PNs) made of cucurbit[6]uril (CB) serve as a versatile platform since various metal nanoparticles (NPs) can be introduced on the surface. They allow for a controlled synthesis, prevent self-aggregation, and provide high stability and dispersibility. Pd@CB-PNs show outstanding properties as heterogeneous catalysts in CC and CN bond-forming reactions in water.
Abstract
A facile synthesis of highly stable, water-dispersible metal-nanoparticle-decorated polymer nanocapsules (M@CB-PNs: M=Pd, Au, and Pt) was achieved by a simple two-step process employing a polymer nanocapsule (CB-PN) made of cucurbit[6]uril (CB[6]) and metal salts. The CB-PN serves as a versatile platform where various metal nanoparticles with a controlled size can be introduced on the surface and stabilized to prepare new water-dispersible nanostructures useful for many applications. The Pd nanoparticles on CB-PN exhibit high stability and dispersibility in water as well as excellent catalytic activity and recyclability in carbon–carbon and carbon–nitrogen bond-forming reactions in aqueous medium suggesting potential applications as a green catalyst.
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