Tandem Synthesis of Photoactive Benzodifuran Moieties in the Formation of Microporous Organic Networks†
Narae Kang
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorDr. Ji Hoon Park
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorKyoung Chul Ko
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorJiseul Chun
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorEunchul Kim
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorDr. Hee-Won Shin
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorDr. Sang Moon Lee
Korea Basic Science Institute, Daejeon 350-333 (Korea)
Search for more papers by this authorDr. Hae Jin Kim
Korea Basic Science Institute, Daejeon 350-333 (Korea)
Search for more papers by this authorCorresponding Author
Prof. Tae Kyu Ahn
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)Search for more papers by this authorCorresponding Author
Prof. Jin Yong Lee
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)Search for more papers by this authorCorresponding Author
Prof. Seung Uk Son
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)Search for more papers by this authorNarae Kang
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorDr. Ji Hoon Park
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorKyoung Chul Ko
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorJiseul Chun
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorEunchul Kim
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorDr. Hee-Won Shin
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Search for more papers by this authorDr. Sang Moon Lee
Korea Basic Science Institute, Daejeon 350-333 (Korea)
Search for more papers by this authorDr. Hae Jin Kim
Korea Basic Science Institute, Daejeon 350-333 (Korea)
Search for more papers by this authorCorresponding Author
Prof. Tae Kyu Ahn
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)Search for more papers by this authorCorresponding Author
Prof. Jin Yong Lee
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)Search for more papers by this authorCorresponding Author
Prof. Seung Uk Son
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)
Department of Chemistry and Department of Energy Science Sungkyunkwan University, Suwon 440-746 (Korea)Search for more papers by this authorThis work was supported by grants NRF-2012-045064 (Midcareer Researcher Program) and R31-2008-10029 (WCU program) through NRF of Korea. J.H.P. thanks for grant NRF-2012-1040282 (Priority Research Centers Program). J.Y.L. acknowledges grant NRF-2007-0056343.
Graphical Abstract
Tiny pores: Benzodifuran moieties were introduced into microporous organic networks (MONs) through a tandem process consisting of Sonogashira coupling of 1,3,5-triethynylbenzene and 2,5-diiodo-1,4-hydroquinone and intramolecular cyclization. The resultant benzodifuran-containing MON showed promising photocatalytic activities in the oxidative conversion of primary amines into imines.
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