A “Smart” Hollandite DeNOx Catalyst: Self-Protection against Alkali Poisoning†
Zhiwei Huang
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorDr. Xiao Gu
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorDr. Wen Wen
Shanghai Synchrotron Radiation Facility, Chinese Academy of Sciences, Shanghai, 201204 (China)
Search for more papers by this authorPingping Hu
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorProf. Michiel Makkee
Catalysis Engineering, Delft University of Technology, Delft, 2628 BL (The Netherlands)
Search for more papers by this authorDr. He Lin
Shanghai Synchrotron Radiation Facility, Chinese Academy of Sciences, Shanghai, 201204 (China)
Search for more papers by this authorProf. Freek Kapteijn
Catalysis Engineering, Delft University of Technology, Delft, 2628 BL (The Netherlands)
Search for more papers by this authorCorresponding Author
Prof. Xingfu Tang
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)Search for more papers by this authorZhiwei Huang
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorDr. Xiao Gu
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorDr. Wen Wen
Shanghai Synchrotron Radiation Facility, Chinese Academy of Sciences, Shanghai, 201204 (China)
Search for more papers by this authorPingping Hu
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorProf. Michiel Makkee
Catalysis Engineering, Delft University of Technology, Delft, 2628 BL (The Netherlands)
Search for more papers by this authorDr. He Lin
Shanghai Synchrotron Radiation Facility, Chinese Academy of Sciences, Shanghai, 201204 (China)
Search for more papers by this authorProf. Freek Kapteijn
Catalysis Engineering, Delft University of Technology, Delft, 2628 BL (The Netherlands)
Search for more papers by this authorCorresponding Author
Prof. Xingfu Tang
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)
Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433 (China)Search for more papers by this authorThis research was supported financially by the NSFC (20977018, 21077026, and 21277032) and the NBRPC (2010CB934501).
Graphical Abstract
Banish the villains to their own realm: Biomass has gained widespread attention as a renewable energy source. However, commercial catalysts used in power plants (co-)fuelled by biomass are deactivated by the alkali-rich flue gas (see graph, black line). In contrast, one of two types of active sites in a promising alkali-resistant hollandite catalyst traps alkali-metal ions to free up the catalytically active sites for the reduction of NO by NH3.
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References
- 1R. Slade, R. Gross, A. Bauen, Energy Environ. Sci. 2011, 4, 2645.
- 2A. Faaij, Energy Policy 2006, 34, 322.
- 3B. Sander, Biomass Bioenergy 1997, 12, 177.
- 4Y. J. Zheng, A. D. Jensen, J. E. Johnsson, Ind. Eng. Chem. Res. 2004, 43, 941.
- 5J. P. Chen, R. T. Yang, J. Catal. 1990, 125, 411.
- 6J. Due-Hansen, S. Boghosian, A. Kustov, P. Fristrup, G. Tsilomelekis, K. Stahl, C. H. Christensen, R. Fehrmann, J. Catal. 2007, 251, 459.
- 7H. Kamata, K. Takahashi, C. Odenbrand, J. Mol. Catal. A 1999, 139, 189.
- 8Y. J. Zheng, A. D. Jensen, J. E. Johnsson, Appl. Catal. B 2005, 60, 253.
- 9S. Putluru, A. Riisager, R. Fehrmann, Appl. Catal. B 2011, 101, 183.
- 10S. Putluru, A. D. Jensen, A. Riisager, R. Fehrmann, Top. Catal. 2011, 54, 1286.
- 11S. Putluru, S. B. Kristensen, J. Due-Hansen, A. Riisager, R. Fehrmann, Catal. Today 2012, 184, 192.
- 12J. A. Moulijn, A. E. Van-Diepen, F. Kapteijn, Appl. Catal. A 2001, 212, 3.
- 13S. Putluru, A. D. Jensen, A. Riisager, R. Fehrmann, Catal. Sci. Technol. 2011, 1, 631.
- 14S. B. Kristensen, A. J. Kunov-Kruse, A. Riisager, S. B. Rasmussen, R. Fehrmann, J. Catal. 2011, 284, 60.
- 15O. Kröcher, M. Elsener, Appl. Catal. B 2008, 77, 215.
- 16Z. M. Wang, S. Tezuka, H. Kanoh, Chem. Mater. 2001, 13, 530.
- 17Z. W. Huang, X. Gu, Q. Q. Cao, P. P. Hu, J. M. Hao, J. H. Li, X. F. Tang, Angew. Chem. 2012, 124, 4274; Angew. Chem. Int. Ed. 2012, 51, 4198.
- 18C. Wang, L. Sun, Q. Q. Cao, B. Q. Hu, Z. W. Huang, X. F. Tang, Appl. Catal. B 2011, 101, 598.
- 19B. Dawson, Proc. R. Soc. London Ser. A 1967, 298, 255.
- 20J. Vicat, E. Fanchon, P. Strobel, D. T. Qui, Acta Crystallogr. Sect. B 1986, 42, 162.
- 21Y. Tanaka, M. Tsuji, Y. Tamaura, Phys. Chem. Chem. Phys. 2000, 2, 1473.
- 22A. Kling, C. Andersson, A. Myringer, D. Eskilsson, S. G. Jaras, Appl. Catal. B 2007, 69, 240.
- 23Y. J. Zheng, P. A. Jensen, A. D. Jensen, B. Sander, H. Junker, Fuel 2007, 86, 1008.
- 24M. Witko, R. Grybos, R. Tokarz-Sobieraj, Top. Catal. 2006, 38, 105.
- 25F. Kapteijn, L. Singoredjo, M. Vandriel, A. Andreini, J. A. Moulijn, G. Ramis, G. Busca, J. Catal. 1994, 150, 105.
- 26P. P. Hu, Z. W. Huang, W. M. Hua, X. Gu, X. F. Tang, Appl. Catal. A 2012, 437–438, 139.
- 27F. Castellino, A. D. Jensen, J. E. Johnsson, R. Fehrmann, Appl. Catal. B 2009, 86, 206.
- 28C. Andersson, C. U. I. Odenbrand, L. H. Andersson, Värmeforsk 1998, 646.
- 29C. Y. Xu, Q. Zhang, H. Zhang, L. Zhen, J. Tang, L. C. Qin, J. Am. Chem. Soc. 2005, 127, 11584.
- 30J. Cai, J. Liu, W. S. Willis, S. L. Suib, Chem. Mater. 2001, 13, 2413.
- 31J. E. Post, R. B. Vondreele, P. R. Buseck, Acta Crystallogr. Sect. B 1982, 38, 1056.
- 32J. Cai, J. Liu, Z. Gao, A. Navrotsky, S. L. Suib, Chem. Mater. 2001, 13, 4595.
