Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal–Organic Framework†
Dr. Natasha F. Sciortino
School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)
Search for more papers by this authorDr. Katrin R. Scherl-Gruenwald
School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)
Search for more papers by this authorDr. Guillaume Chastanet
Sciences Moléculaires, ICMCB, UPR CNRS 9048, Université Bordeaux I, 87 Av. Du Doc. A. Schweitzer, 33608 Pessac (France)
Search for more papers by this authorDr. Gregory J. Halder
X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439 (USA)
Search for more papers by this authorDr. Karena W. Chapman
X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439 (USA)
Search for more papers by this authorProf. Jean-François Létard
Sciences Moléculaires, ICMCB, UPR CNRS 9048, Université Bordeaux I, 87 Av. Du Doc. A. Schweitzer, 33608 Pessac (France)
Search for more papers by this authorCorresponding Author
Prof. Cameron J. Kepert
School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)
School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)Search for more papers by this authorDr. Natasha F. Sciortino
School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)
Search for more papers by this authorDr. Katrin R. Scherl-Gruenwald
School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)
Search for more papers by this authorDr. Guillaume Chastanet
Sciences Moléculaires, ICMCB, UPR CNRS 9048, Université Bordeaux I, 87 Av. Du Doc. A. Schweitzer, 33608 Pessac (France)
Search for more papers by this authorDr. Gregory J. Halder
X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439 (USA)
Search for more papers by this authorDr. Karena W. Chapman
X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439 (USA)
Search for more papers by this authorProf. Jean-François Létard
Sciences Moléculaires, ICMCB, UPR CNRS 9048, Université Bordeaux I, 87 Av. Du Doc. A. Schweitzer, 33608 Pessac (France)
Search for more papers by this authorCorresponding Author
Prof. Cameron J. Kepert
School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)
School of Chemistry, The University of Sydney, Sydney NSW 2006 (Australia)Search for more papers by this authorUse of the Advanced Photon Source was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. N.F.S. thanks to the Australian Nanotechnology Network for financial support. K.R.G. thanks the Endeavour Research Fellowship for financial support.
Graphical Abstract
Multistability is exhibited by a metal–organic framework material that undergoes unique three-step spin crossover with 20 K thermal hysteresis (see picture). The stepwise transition is coupled to a three-step structural transformation that defines four distinct structural states. The material also exhibits reversible photo-induced spin crossover.
Supporting Information
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