Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds†
Dr. Sébastien Bontemps
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorDr. Laure Vendier
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorCorresponding Author
Dr. Sylviane Sabo-Etienne
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433Search for more papers by this authorDr. Sébastien Bontemps
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorDr. Laure Vendier
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorCorresponding Author
Dr. Sylviane Sabo-Etienne
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433Search for more papers by this authorWe thank the ANR (Programme blanc “HyBoCat” ANR-09-BLAN-0184), the CNRS for support, and Johnson Matthey plc for the generous gift of hydrated ruthenium trichloride.
Graphical Abstract
One and two: The C2 compound pinBOCH2OCHO (see scheme; HBpin=pinacolborane) and several C1 compounds have been obtained from the borane-mediated reduction of CO2 under mild conditions with the catalyst precursor [RuH2(H2)2(PCy3)2]. Mechanistic investigation highlights the role of a series of new carbonyl ruthenium complexes that were characterized by multinuclear NMR spectroscopy, IR spectroscopy, and X-ray diffraction studies.
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
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