Metal–Organic Conjugated Microporous Polymers†
Dr. Jia-Xing Jiang
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorChao Wang
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorAndrea Laybourn
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorDr. Tom Hasell
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorRob Clowes
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorDr. Yaroslav Z. Khimyak
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorProf. Jianliang Xiao
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorDr. Simon J. Higgins
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorDr. Dave J. Adams
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorCorresponding Author
Prof. Andrew I. Cooper
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304Search for more papers by this authorDr. Jia-Xing Jiang
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorChao Wang
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorAndrea Laybourn
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorDr. Tom Hasell
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorRob Clowes
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorDr. Yaroslav Z. Khimyak
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorProf. Jianliang Xiao
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorDr. Simon J. Higgins
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorDr. Dave J. Adams
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Search for more papers by this authorCorresponding Author
Prof. Andrew I. Cooper
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool (UK), Fax: (+44) 151-794-2304Search for more papers by this authorWe gratefully acknowledge the EPSRC for funding (EP/F057865/1 and EP/H000925).
Graphical Abstract
Two versatile strategies for preparing metal–organic conjugated microporous polymers (MO-CMPs) containing metals such as rhenium, rhodium, and iridium are described (see example). These materials combine the uninterrupted extended electronic conjugation in the network with catalytically active metal sites.
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
| Filename | Description |
|---|---|
| anie_201005864_sm_miscellaneous_information.pdf1.7 MB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aN. B. McKeown, P. M. Budd, Chem. Soc. Rev. 2006, 35, 675;
- 1bJ. Germain, J. M. J. Fréchet, F. Svec, Small 2009, 5, 1098;
- 1cR. E. Morris, P. S. Wheatley, Angew. Chem. 2008, 120, 5044; Angew. Chem. Int. Ed. 2008, 47, 4966.
- 2
- 2aO. M. Yaghi, H. L. Li, C. Davis, D. Richardson, T. L. Groy, Acc. Chem. Res. 1998, 31, 474;
- 2bP. J. Langley, J. Hulliger, Chem. Soc. Rev. 1999, 28, 279;
- 2cM. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O’Keeffe, O. M. Yaghi, Science 2002, 295, 469;
- 2dX. B. Zhao, B. Xiao, A. J. Fletcher, K. M. Thomas, D. Bradshaw, M. J. Rosseinsky, Science 2004, 306, 1012.
- 3A. P. Côté, A. I. Benin, N. W. Ockwig, M. O’Keeffe, A. J. Matzger, O. M. Yaghi, Science 2005, 310, 1166.
- 4
- 4aJ. X. Jiang, F. Su, A. Trewin, C. D. Wood, N. L. Campbell, H. Niu, C. Dickinson, A. Y. Ganin, M. J. Rosseinsky, Y. Z. Khimyak, A. I. Cooper, Angew. Chem. 2007, 119, 8728; Angew. Chem. Int. Ed. 2007, 46, 8574;
- 4bJ. Y. Lee, C. D. Wood, D. Bradshaw, M. J. Rosseinsky, A. I. Cooper, Chem. Commun. 2006, 2670;
- 4cN. B. McKeown, B. Gahnem, K. J. Msayib, P. M. Budd, C. E. Tattershall, K. Mahmood, S. Tan, D. Book, H. W. Langmi, A. Walton, Angew. Chem. 2006, 118, 1836;
10.1002/ange.200504241 Google ScholarAngew. Chem. Int. Ed. 2006, 45, 1804;
- 4dJ. Germain, J. M. J. Fréchet, F. Svec, J. Mater. Chem. 2007, 17, 4989;
- 4eC. E. Chan-Thaw, A. Villa, P. Katekomol, D. S. Su, A. Thomas, L. Prati, Nano Lett. 2010, 10, 537.
- 5
- 5aJ. L. Atwood, L. J. Barbour, A. Jerga, Science 2002, 296, 2367;
- 5bT. Tozawa, J. T. A. Jones, S. I. Swamy, S. Jiang, D. J. Adams, S. Shakespeare, R. Clowes, D. Bradshaw, T. Hasell, S. Y. Chong, C. Tang, S. Thompson, J. Parker, A. Trewin, J. Bacsa, A. M. Z. Slawin, A. Steiner, A. I. Cooper, Nat. Mater. 2009, 8, 973;
- 5cJ. R. Holst, A. Trewin, A. I. Cooper, Nat. Chem. 2010, 2, 915.
- 6R. Dawson, A. Laybourn, R. Clowes, Y. Z. Khimyak, D. J. Adams, A. I. Cooper, Macromolecules 2009, 42, 8809.
- 7
- 7aJ. X. Jiang, F. Su, A. Trewin, C. D. Wood, H. Niu, J. T. A. Jones, Y. Z. Khimyak, A. I. Cooper, J. Am. Chem. Soc. 2008, 130, 7710;
- 7bR. Dawson, F. B. Su, H. J. Niu, C. D. Wood, J. T. A. Jones, Y. Z. Khimyak, A. I. Cooper, Macromolecules 2008, 41, 1591;
- 7cJ. Weber, A. Thomas, J. Am. Chem. Soc. 2008, 130, 6334;
- 7dT. Ben, H. Ren, S. Q. Ma, D. P. Cao, J. H. Lan, X. F. Jing, W. C. Wang, J. Xu, F. Deng, J. M. Simmons, S. L. Qiu, G. S. Zhu, Angew. Chem. 2009, 121, 9621; Angew. Chem. Int. Ed. 2009, 48, 9457;
- 7eJ. Schmidt, J. Weber, J. D. Epping, M. Antonietti, A. Thomas, Adv. Mater. 2009, 21, 702;
- 7fJ. Schmidt, M. Werner, A. Thomas, Macromolecules 2009, 42, 4426;
- 7gL. Chen, Y. Honsho, S. Seki, D. L. Jiang, J. Am. Chem. Soc. 2010, 132, 6742;
- 7hJ. R. Holst, E. Stöckel, D. J. Adams, A. I. Cooper, Macromolecules 2010, 43, 8531.
- 8Ref. [7g].
- 9aT. Hasell, C. D. Wood, R. Clowes, J. T. A. Jones, Y. Z. Khimyak, D. J. Adams, A. I. Cooper, Chem. Mater. 2010, 22, 557;
- 9bA. Li, R. F. Lu, Y. Wang, X. Wang, K. L. Han, W. Q. Deng, Angew. Chem. 2010, 122, 3402; Angew. Chem. Int. Ed. 2010, 49, 3330.
- 10L. Chen, Y. Yang, D. L. Jiang, J. Am. Chem. Soc. 2010, 132, 9138.
- 11L. A. Worl, R. Duesing, P. Y. Chen, L. Dellaciana, T. J. Meyer, J. Chem. Soc. Dalton Trans. 1991, 849.
- 12
- 12aJ. X. Jiang, F. Su, H. Niu, C. D. Wood, N. L. Campbell, Y. Z. Khimyak, A. I. Cooper, Chem. Commun. 2008, 486;
- 12bA. I. Cooper, Adv. Mater. 2009, 21, 1291;
- 12cJ. X. Jiang, A. Trewin, F. B. Su, C. D. Wood, H. J. Niu, J. T. A. Jones, Y. Z. Khimyak, A. I. Cooper, Macromolecules 2009, 42, 2658;
- 12dE. Stöckel, X. F. Wu, A. Trewin, C. D. Wood, R. Clowes, N. L. Campbell, J. T. A. Jones, Y. Z. Khimyak, D. J. Adams, A. I. Cooper, Chem. Commun. 2009, 212.
- 13A. M. Spokoyny, D. Kim, A. Sumrein, C. A. Mirkin, Chem. Soc. Rev. 2009, 38, 1218.
- 14H. Furukawa, N. Ko, Y. B. Go, N. Aratani, S. B. Choi, E. Choi, A. O. Yazaydin, R. Q. Snurr, M. O’Keeffe, J. Kim, O. M. Yaghi, Science 2010, 329, 424.
- 15Y. M. Jeon, G. S. Armatas, J. Heo, M. G. Kanatzidis, C. A. Mirkin, Adv. Mater. 2008, 20, 2105.
- 16
- 16aJ. X. Jiang, W. Yang, Y. Cao, J. Inorg. Organomet. Polym. Mater. 2007, 17, 37;
- 16bX. Gong, M. R. Robinson, J. C. Ostrowski, D. Moses, G. C. Bazan, A. J. Heeger, Adv. Mater. 2002, 14, 581.
- 17X. Du, Y. L. Sun, B. E. Tan, Q. F. Teng, X. J. Yao, C. Y. Su, W. Wang, Chem. Commun. 2010, 46, 970.
- 18C. Wang, A. Pettman, J. Basca, J. Xiao, Angew. Chem. 2010, 122, 7710; Angew. Chem. Int. Ed. 2010, 49, 7548.
- 19
- 19aH. Y. Wang, W. G. Wang, G. Si, F. Wang, C. H. Tung, L. Z. Wu, Langmuir 2010, 26, 9766;
- 19bY. Yamamoto, Y. Tamaki, T. Yui, K. Koike, O. Ishitani, J. Am. Chem. Soc. 2010, 132, 11743.
