Volume 48, Issue 24 pp. 4341-4343
Communication

Nuclear Spin-Noise Spectra of Hyperpolarized Systems

Hervé Desvaux Prof.

Hervé Desvaux Prof.

CEA, IRAMIS, Service Interdisciplinaire sur le Systèmes Moléculaires et les Matériaux, Laboratoire Structure et Dynamique par Résonance Magnétique, URA CEA/CNRS 331, 91191 Gif-sur-Yvette (France), Fax: (+33) 1-6908-9806, http://iramis.cea.fr/Pisp/59/herve.desvaux.html

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Denis J. Y. Marion Dr.

Denis J. Y. Marion Dr.

CEA, IRAMIS, Service Interdisciplinaire sur le Systèmes Moléculaires et les Matériaux, Laboratoire Structure et Dynamique par Résonance Magnétique, URA CEA/CNRS 331, 91191 Gif-sur-Yvette (France), Fax: (+33) 1-6908-9806, http://iramis.cea.fr/Pisp/59/herve.desvaux.html

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Gaspard Huber Dr.

Gaspard Huber Dr.

CEA, IRAMIS, Service Interdisciplinaire sur le Systèmes Moléculaires et les Matériaux, Laboratoire Structure et Dynamique par Résonance Magnétique, URA CEA/CNRS 331, 91191 Gif-sur-Yvette (France), Fax: (+33) 1-6908-9806, http://iramis.cea.fr/Pisp/59/herve.desvaux.html

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Patrick Berthault Dr.

Patrick Berthault Dr.

CEA, IRAMIS, Service Interdisciplinaire sur le Systèmes Moléculaires et les Matériaux, Laboratoire Structure et Dynamique par Résonance Magnétique, URA CEA/CNRS 331, 91191 Gif-sur-Yvette (France), Fax: (+33) 1-6908-9806, http://iramis.cea.fr/Pisp/59/herve.desvaux.html

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First published: 26 May 2009
Citations: 24

We thank Dr. Dimitrios Sakellariou for technical comments on the preparation of the microcoils. Financial support from the French Ministry of Research (ANR program “Physico-Chimie du Vivant 2006” and program “Blanc 2007”) is greatly acknowledged.

Graphical Abstract

Spin-noise appeal: Detection of NMR spin-noise is very appealing when dilute hyperpolarized species are considered. Continuous monitoring of the noise absorption at the Larmor frequency enables determination of T1 and T2*, independently of the static magnetic field. An inductively coupled microcoil located inside the NMR tube (see picture) allows acquisition of 129Xe spin-noise spectra without radio-frequency excitation.

Abstract

Spin-noise appeal: Detection of NMR spin-noise is very appealing when dilute hyperpolarized species are considered. Continuous monitoring of the noise absorption at the Larmor frequency enables determination of T1 and T2*, independently of the static magnetic field. An inductively coupled microcoil located inside the NMR tube (see picture) allows acquisition of 129Xe spin-noise spectra without radio-frequency excitation.

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