Phosphinoborane and Sulfidoborohydride as Chelating Ligands in Polyhydride Ruthenium Complexes: Agostic σ-Borane versus Dihydroborate Coordination†
Yann Gloaguen
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorGilles Alcaraz Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorAnne-Frédérique Pécharman
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorEric Clot Dr.
Université Montpellier 2, Institut Charles Gerhardt, CNRS 5253, cc 1501, Place Eugène Bataillon, 34095 Montpellier (France)
Search for more papers by this authorLaure Vendier Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorSylviane Sabo-Etienne Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorYann Gloaguen
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorGilles Alcaraz Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorAnne-Frédérique Pécharman
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorEric Clot Dr.
Université Montpellier 2, Institut Charles Gerhardt, CNRS 5253, cc 1501, Place Eugène Bataillon, 34095 Montpellier (France)
Search for more papers by this authorLaure Vendier Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorSylviane Sabo-Etienne Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorWe thank the CNRS and the ANR (programme blanc ANR-06-BLAN-0060-01) for support (Y.G., G.A., L.V., S.S.E.)
Graphical Abstract
A question of coordination mode: Two new borane compounds are prepared. They act as bifunctional ligands as illustrated by their reaction with ruthenium polyhydrides which leads to the formation of two complexes (see scheme) displaying either a δ-agostic interaction of a η2-BH bond involving a trivalent boron atom or a dihydroborate ligation.
Abstract
A question of coordination mode: Two new borane compounds are prepared. They act as bifunctional ligands as illustrated by their reaction with ruthenium polyhydrides which leads to the formation of two complexes (see scheme) displaying either a δ-agostic interaction of a η2-BH bond involving a trivalent boron atom or a dihydroborate ligation.
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