Volume 46, Issue 12 p. 1927

Cover Picture: Interpenetrating Polar and Nonpolar Sublattices in Intermetallics: The NaCd2 Structure (Angew. Chem. Int. Ed. 12/2007)

Daniel C. Fredrickson Dr.

Daniel C. Fredrickson Dr.

Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853-1301, USA, Fax: (+1) 607-255-4137

Present address: Department of Inorganic Chemistry Stockholm University 106 91 Stockholm, Sweden

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Stephen Lee Prof.

Stephen Lee Prof.

Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853-1301, USA, Fax: (+1) 607-255-4137

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Roald Hoffmann Prof.

Roald Hoffmann Prof.

Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853-1301, USA, Fax: (+1) 607-255-4137

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First published: 02 March 2007
Citations: 2

Abstract

The sun and the moon are not quite equal partners; the two clusters shown in the cover picture are more so. They rise and set in several incredibly complex intermetallic phases, such as NaCd2. As explained by R. Hoffmann and co-workers in their Review on page 1958 ff., an electronic Aufbau based on these clusters generates the full NaCd2 structure in all its glory: the clusters build two interpenetrating networks that strive for the extremes of polarity and nonpolarity. The alchemical image, drawn by Robert Vaughn, is from Elias Ashmole's Theatricum Chemicum Britannicum.

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