Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies†
Xiao-Chun Huang Dr.
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China
Search for more papers by this authorYan-Yong Lin
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorJie-Peng Zhang Dr.
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorXiao-Ming Chen Prof. Dr.
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorXiao-Chun Huang Dr.
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China
Search for more papers by this authorYan-Yong Lin
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorJie-Peng Zhang Dr.
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorXiao-Ming Chen Prof. Dr.
State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China, Fax: (+86) 20-8411-2245
Search for more papers by this authorThis work was supported by the National Natural Science Foundation of China (No. 20531070) and the Guangdong Provincial Science and Technology Bureau (No. 04205405).
Graphical Abstract
Thermally robust porous metal–organic frameworks (MOFs) with zeolitic topologies were constructed by means of a ligand-directed strategy involving molecular tailoring of simple bridging imidazolates with coordinatively unimportant substituents. This led to the isolation of three new MOFs having unusually high symmetries, intriguing topologies such as the supercage shown in the picture, and high thermal stability.
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Citing Literature
February 27, 2006
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