A Germanate Framework Containing 24-Ring Channels, NiGe Bonds, and Chiral [Ni@Ge14O24(OH)3] Cluster Motifs Transferred from Chiral Metal Complexes†
Zhi-En Lin
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorJie Zhang Prof. Dr.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorJing-Tai Zhao Prof. Dr.
State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China
Search for more papers by this authorShou-Tian Zheng
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorChun-Yang Pan
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorGuo-Ming Wang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorGuo-Yu Yang Prof. Dr.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorZhi-En Lin
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorJie Zhang Prof. Dr.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorJing-Tai Zhao Prof. Dr.
State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China
Search for more papers by this authorShou-Tian Zheng
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorChun-Yang Pan
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorGuo-Ming Wang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorGuo-Yu Yang Prof. Dr.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
Search for more papers by this authorThis work was supported by the NNSF of China (Nos. 20473093 and 20271050), the Talents Program of Chinese Academy of Sciences, and the NSF of Fujian Province (Nos. E0510030 and E0210029).
Graphical Abstract
Microporous: Chiral metal complexes as templates under solvothermal conditions resulted in two novel germanates Ni@Ge14O24(OH)3⋅2 Ni(L)3 (L=ethylenediamine, 1,2-diaminopropane). The chiral Ni@Ge14O24(OH)3 cluster motifs have an unprecedented trigonal-bipyramidal Ni@Ge5 core with NiGe bonds and are linked to each other to form a 3D germanate framework containing 24-ring channels (see picture).
Supporting Information
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Citing Literature
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