Vapochromic Behavior Accompanied by Phase Transition between Charge-Polarization and Charge-Density-Wave States in a Quasi-One-Dimensional Iodine-Bridged Dinuclear Platinum Compound†
Hiroyuki Mastuzaki Dr.
Department of Advanced Materials Science, Graduate School of Frontier Sciences, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan, Fax: (+81) 4-7136-3773
Search for more papers by this authorHideo Kishida Dr.
Department of Advanced Materials Science, Graduate School of Frontier Sciences, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan, Fax: (+81) 4-7136-3773
Search for more papers by this authorHiroshi Okamoto Prof. Dr.
Department of Advanced Materials Science, Graduate School of Frontier Sciences, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan, Fax: (+81) 4-7136-3773
Search for more papers by this authorKouichi Takizawa
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorSatoshi Matsunaga
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorShinya Takaishi Dr.
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorHitoshi Miyasaka Dr.
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorKen-ichi Sugiura Prof. Dr.
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorMasahiro Yamashita Prof. Dr.
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorHiroyuki Mastuzaki Dr.
Department of Advanced Materials Science, Graduate School of Frontier Sciences, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan, Fax: (+81) 4-7136-3773
Search for more papers by this authorHideo Kishida Dr.
Department of Advanced Materials Science, Graduate School of Frontier Sciences, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan, Fax: (+81) 4-7136-3773
Search for more papers by this authorHiroshi Okamoto Prof. Dr.
Department of Advanced Materials Science, Graduate School of Frontier Sciences, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan, Fax: (+81) 4-7136-3773
Search for more papers by this authorKouichi Takizawa
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorSatoshi Matsunaga
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorShinya Takaishi Dr.
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorHitoshi Miyasaka Dr.
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorKen-ichi Sugiura Prof. Dr.
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorMasahiro Yamashita Prof. Dr.
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minamiohsawa, Hachioji, Tokyo 192-0397, Japan
CREST (JST), Kawaguchi, Saitama 332-0012, Japan
Search for more papers by this authorThis work was partly supported by a Grant-in-Aid for Creative Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology.
Graphical Abstract
Color sense: A reversible phase transition occurs with a change in color and structural properties on exposure to water vapor of the 1D halogen-bridged dinuclear platinum compound [NH3(C4H8)NH3]2[Pt2(pop)4I]⋅4 H2O (pop=P2O5H22−; see microscope images in reflection mode). This transition takes place between a paramagnetic charge-polarization state (296 K) and a diamagnetic charge-density-wave state (340 K).
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