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Tri- and Tetracarbanionic Initiators by a Lithium/Halide Exchange Reaction: Application to Star-Polymer Synthesis^†

Rachid Matmour

Laboratoire de Chimie des Polymères Organiques, École Nationale Supérieure de Chimie et Physique de Bordeaux, Université Bordeaux 1, 16 Avenue Pey-Berland, 33607 Pessac, France, Fax: (+33) 5-4000-8487

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Arnaud Lebreton Dr.,

Arnaud Lebreton Dr.

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Constantinos Tsitsilianis Prof.,

Constantinos Tsitsilianis Prof.

Department of Chemical Engineering, University of Patras, 26504 Patras, Greece

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Ioannis Kallitsis Prof.,

Ioannis Kallitsis Prof.

Department of Chemistry, University of Patras, 26504 Patras, Greece

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Valérie Héroguez Dr.,

Valérie Héroguez Dr.

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Yves Gnanou Prof.,

Yves Gnanou Prof.

[email protected]

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Rachid Matmour,

Rachid Matmour

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Arnaud Lebreton Dr.,

Arnaud Lebreton Dr.

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Constantinos Tsitsilianis Prof.,

Constantinos Tsitsilianis Prof.

Department of Chemical Engineering, University of Patras, 26504 Patras, Greece

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Ioannis Kallitsis Prof.,

Ioannis Kallitsis Prof.

Department of Chemistry, University of Patras, 26504 Patras, Greece

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Valérie Héroguez Dr.,

Valérie Héroguez Dr.

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Yves Gnanou Prof.,

Yves Gnanou Prof.

[email protected]

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First published: 21 December 2004

https://doi.org/10.1002/anie.200461056

Citations: 39

^†

The authors thank the CNRS and the French Ministry of Research for support of this research.

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Graphical Abstract

A family of polycarbanionic initiators: Bis-, tris-, and tetrakisaryl lithium compounds (see scheme) were synthesized from the corresponding aryl halides by simple halogen/lithium exchange reactions. These polylithiated species were used to prepare telechelic and three- and four-armed star polystyrene and polybutadiene homopolymers, as well as poly(styrene-block-butadiene-block-methyl methacrylate) star block terpolymers.

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Volume44, Issue2

December 27, 2004

Pages 284-287

Tri- and Tetracarbanionic Initiators by a Lithium/Halide Exchange Reaction: Application to Star-Polymer Synthesis^†

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Tri- and Tetracarbanionic Initiators by a Lithium/Halide Exchange Reaction: Application to Star-Polymer Synthesis†

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Tri- and Tetracarbanionic Initiators by a Lithium/Halide Exchange Reaction: Application to Star-Polymer Synthesis^†