Polymer–Monomer Pairs as a Reaction System for the Synthesis of Magnetic Fe3O4–Polymer Hybrid Hollow Nanospheres†
Yin Ding
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorYong Hu Dr.
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorXiqun Jiang Prof.
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorLeyang Zhang
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorChangzheng Yang Prof.
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorYin Ding
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorYong Hu Dr.
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorXiqun Jiang Prof.
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorLeyang Zhang
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorChangzheng Yang Prof.
Laboratory of Mesoscopic Chemistry and Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. China, Fax: (+86) 25-8331-7761
Search for more papers by this authorSupported by the Natural Science Foundation of China (No. 20 374 026, No. 10 334 020) and the 973 Program of MOST (No.2003 CB 615 600).
Graphical Abstract
Magnetic hollow Fe3O4–polymer hybrid nanospheres (see figure) were prepared by adding Fe3O4 nanoparticles to an aqueous solution of polymer–monomer pairs composed of a cationic polymer (chitosan) and an anionic monomer (acrylic acid), followed by polymerization of acrylic acid and selective crosslinking of chitosan at the end of the polymerization.
References
- 1 Hollow and Solid Spheres and Microspheres: Science and Technology Associated with Their Fabrication and Application, Vol. 372 (Eds.: ), Materials Research Society Proceedings, Pittsburgh, 1995.
- 2J. Okada, S. Cohen, R. Langer, Pharm. Res. 1994, 11, 1568.
- 3T. Ameller, W. Marsaud, P. Legrand, R. Gref, J. M. Renoir, Int. J. Cancer 2003, 106, 446.
- 4I. Gill, A. Ballesteros, J. Am. Chem. Soc. 1998, 120, 8587.
- 5T. Visted, T. Furmanek, P. Sakariassen, W. B. Foegler, K. Sim, H. Westphal, R. Bjerkvig, M. Lund-Johansen, Hum. Gene Ther. 2003, 14, 1429.
- 6P. Tartaj, M. P. Morales, S. Veintemillas-Verdaguer, T. Gonzalez-Carreno, C. J. Serna, J. Phys. D 2003, 36, R 182.
- 7S. M. Marinakos, M. F. Anderson, J. A. Ryan, L. D. Martin, D. L. Feldheim, J. Phys. Chem. B 2001, 105, 8872.
- 8F. Caruso, Top. Curr. Chem. 2003, 227, 145.
- 9H. Huang, E. E. Remsen, T. Kowalewski, K. L. Wooley, J. Am. Chem. Soc. 1999, 121, 3805.
- 10H. Shiho, N. Kawahashi, J. Colloid Interface Sci. 2000, 226, 91.
- 11
- 11aH. Dou, M. Jiang, H. Peng, D. Chen, Y. Hong, Angew. Chem. 2003, 115, 1554; Angew. Chem. Int. Ed. 2003, 42, 1516;
- 11bX. Liu, M. Jiang, S. Yang, M. Chen, D. Chen, C. Yang, K. Wu, Angew. Chem. 2002, 114, 3074;
Angew. Chem. Int. Ed. 2002, 41, 2950.
10.1002/1521-3773(20020816)41:16<2950::AID-ANIE2950>3.0.CO;2-K CAS PubMed Web of Science® Google Scholar
- 12
- 12aZ. Z. Zhong, Y. D. Yin, B. Gates, Y. Xia, Adv. Mater. 2000, 12, 206;
- 12bI. Tissot, J. P. Reymond, F. Lefebvre, E. Bourgeat-Lami, Chem. Mater. 2002, 14, 1325;
- 12cA. Imhof, Langmuir 2001, 17, 3579;
- 12dH. Shiho, N. Kawahashi, Colloid Polym. Sci. 2000, 278, 270;
- 12eH. Sertchook, D. Avnir, Chem. Mater. 2003, 15, 1690;
- 12fZ. Yang, Z. Niu, Y. Lu, Z. Hu, C. C. Han, Angew. Chem. 2003, 115, 1987; Angew. Chem. Int. Ed. 2003, 42, 1943.
- 13
- 13aF. Caruso, R. A. Caruso, H. Mohwald, Science 1998, 282, 1111;
- 13bN. Kawahashi, E. Matijevic, J. Colloid Interface Sci. 1990, 138, 534;
- 13cF. Caruso, M. Spasova, A. Susha, M. Giersig, R. A. Caruso, Chem. Mater. 2001, 13, 109.
- 14M. S. Wong, J. N. Cha, K. S. Choi, T. J. Deming, G. D. Stucky, Nanolett. 2002, 2, 583.
- 15J. N. Cha, H. Birkedal, L. E. Euliss, M. H. Bartl, M. S. Wong, T. J. Deming, G. D. Stucky, J. Am. Chem. Soc. 2003, 125, 8285.
- 16H. Strohm, M. Sgraja, J. Bertling, P. Lobmann, J. Mater. Sci. 2003, 38, 1605.
- 17Y. Hu, X. Jiang, Y. Ding, Q. Chen, C. Z. Yang, Adv. Mater. 2004, 16, 933.
- 18W. Arguelles-Monal, C. Peniche-Covas, Makromol. Chem. Rapid Commun. 1988, 9, 693.
