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Zeolite Encaged Cu(Histidine) Complexes as Mimics of Natural Cu Enzymes^†

Corresponding Author

Dr. Bert M. Weckhuysen

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]Search for more papers by this author

An A. Verberckmoes,

An A. Verberckmoes

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Ina P. Vannijvel,

Ina P. Vannijvel

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Josephina A. Pelgrims,

Josephina A. Pelgrims

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Dr. Philip L. Buskens,

Dr. Philip L. Buskens

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Prof. Pierre A. Jacobs,

Prof. Pierre A. Jacobs

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Prof. Robert A. Schoonheydt,

Prof. Robert A. Schoonheydt

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Dr. Bert M. Weckhuysen,

Corresponding Author

Dr. Bert M. Weckhuysen

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

An A. Verberckmoes,

An A. Verberckmoes

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Ina P. Vannijvel,

Ina P. Vannijvel

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Josephina A. Pelgrims,

Josephina A. Pelgrims

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Dr. Philip L. Buskens,

Dr. Philip L. Buskens

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Prof. Pierre A. Jacobs,

Prof. Pierre A. Jacobs

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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Prof. Robert A. Schoonheydt,

Prof. Robert A. Schoonheydt

Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kardinaal Mercierlaan 92, B-3001 Heverlee (Belgium), Telefax: Int. code + (16)32 19 98, e-mail: [email protected]

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First published: January 5, 1996

https://doi.org/10.1002/anie.199526521

Citations: 58

^†

This work was supported by the Belgian Government in the frame of a Interuniversity Attraction Pole (IUAP). We are indebted to N. F. W. O. (B. M. W.) and I. W. T. (A.A.V.) for fellowships as research assistants.

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Graphical Abstract

Epoxidations of olefins and oxidations of alcohols can be carried out in the presence of peroxides at relatively low temperatures with Cu²⁺ histidine complexes that have been immobilized in zeolite cavities (structure from molecular modeling shown on the right). Combined diffuse reflectance and ESR spectroscopic studies reveal the presence of three nitrogen atoms in the first coordination sphere of Cu²⁺.

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Volume34, Issue23-24

January 5, 1996

Pages 2652-2654

Zeolite Encaged Cu(Histidine) Complexes as Mimics of Natural Cu Enzymes^†

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Zeolite Encaged Cu(Histidine) Complexes as Mimics of Natural Cu Enzymes†

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Zeolite Encaged Cu(Histidine) Complexes as Mimics of Natural Cu Enzymes^†