New Selenolato-Bridged Clusters of Iron and Nickel; the Structures of [Fe12(SePh)24] and [Na2(POPh3)6][Ni20Se12(SeMe)10]†‡
Corresponding Author
Prof. Dr. Dieter Fenske
Institut für Anorganische Chemie der Universität, Engesserstrasse, Geb.-Nr. 30.45, D-76128 Karlsruhe (Germany) Telefax: Int. code + (721)661921
Institut für Anorganische Chemie der Universität, Engesserstrasse, Geb.-Nr. 30.45, D-76128 Karlsruhe (Germany) Telefax: Int. code + (721)661921Search for more papers by this authorDipl.-Chem. Andreas Fischer
Institut für Anorganische Chemie der Universität, Engesserstrasse, Geb.-Nr. 30.45, D-76128 Karlsruhe (Germany) Telefax: Int. code + (721)661921
Search for more papers by this authorCorresponding Author
Prof. Dr. Dieter Fenske
Institut für Anorganische Chemie der Universität, Engesserstrasse, Geb.-Nr. 30.45, D-76128 Karlsruhe (Germany) Telefax: Int. code + (721)661921
Institut für Anorganische Chemie der Universität, Engesserstrasse, Geb.-Nr. 30.45, D-76128 Karlsruhe (Germany) Telefax: Int. code + (721)661921Search for more papers by this authorDipl.-Chem. Andreas Fischer
Institut für Anorganische Chemie der Universität, Engesserstrasse, Geb.-Nr. 30.45, D-76128 Karlsruhe (Germany) Telefax: Int. code + (721)661921
Search for more papers by this authorThis work was supported by the Deutsche Forschungsgemeinschaft (Sonderforschungsbereich 195) and the Fonds der Chemischen Industrie.
Dedicated to Professor Dr. Gerhard Fritz on the occasion of his 75th birthday
Graphical Abstract
A twelve-membered ring made up of Fe2+ ions is present in the cluster framework of 1 (shown on the right without phenyl groups; Fe atoms are white, Se atoms shaded). The Fe2+ ions are located in the centers of edge-sharing Se4 tetrahedra, which in turn form a ring. The shiny black needles of 1 are prepared from FeCl3, PPh3, and PhSeSiMe3, and decompose readily upon heating.
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