Volume 17, Issue 11 pp. 820-825
Review
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Polyethylene Fibrids: Preparation and Properties

Dr. Wolfgang Gordon

Dr. Wolfgang Gordon

Hoechst AG, Kunststoff-Forschung, Postfach 8003 20, D-6230 Frankfurt am Main 80 (Germany)

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Dr. Hans Joachim Leugering

Dr. Hans Joachim Leugering

Hoechst AG, Kunststoff-Forschung, Postfach 8003 20, D-6230 Frankfurt am Main 80 (Germany)

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Prof. Dr. Harald Cherdron

Corresponding Author

Prof. Dr. Harald Cherdron

Hoechst AG, Kunststoff-Forschung, Postfach 8003 20, D-6230 Frankfurt am Main 80 (Germany)

Hoechst AG, Kunststoff-Forschung, Postfach 8003 20, D-6230 Frankfurt am Main 80 (Germany)Search for more papers by this author
First published: November 1978
Citations: 2

Main lecture at the GDCh General Meeting, September 13, 1977 in München (Germany).

Dedicated to Professor Karl Winnacker on the occasion of his 75th birthday

Graphical Abstract

Polyethylene fibrids are small, highly oriented fibers formed on shear-induced crystallization of polyethylene. They have interesting properties.

Abstract

Polyethylene fibrids are small fibers having lengths of up to some millimeters, which are highly oriented and which have a morphology similar to that of cellulose fibers. The preparation of polyethylene fibrids is based on shear-induced crystallization, a process in which the polyethylene crystallizes from solution under the influence of an elongated flow in the form of so-called shish-kebabs. Polymerization under shear conditions and the flash spinning of polyethylene solutions are the main processes for the preparation of PE fibrids. They may be hydrophilized by an additional process step.—Because of their cellulose-like morphology, (hydrophilized) polyethylene fibrids have interesting properties, e.g. high adsorption capacity and the ability to form hydrogen bonds. In addition, the possibility of undertaking chemical reactions on the surface of the fibrids should be mentioned.

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