Review
Full Access
Syntheses of Oxide Halides
Dr. K. Dehnicke,
Dr. K. Dehnicke
Laboratorium für Anorganische Chemie der Technischen Hochschule, Stuttgart (Germany)
Search for more papers by this authorDr. K. Dehnicke,
Dr. K. Dehnicke
Laboratorium für Anorganische Chemie der Technischen Hochschule, Stuttgart (Germany)
Search for more papers by this authorAbstract
Knowledge of the oxide halides has made significant advances in recent years as a result of new methods of preparation. Moreover, the systematic study of older methods has led to versatile syntheses which permit the preparation of many new oxide halides. A brief outline of the scope, limitations, and difficulties of the various processes is given together with a number of examples.
References
- 1 C. A. Wurtz, Ann. Chim. physique 20, 472 (1847).
- 2 E. Fluck, Angew. Chem. 72, 752 (1960).
- 3 R. Rheinboldt and W. Wisfeld, Liebigs Ann. Chem. 517, 197 (1935).
- 4 W. C. Schumb and D. F. Holloway, J. Amer. chem. Soc. 63, 2753 (1941).
- 5 W. C. Schumb and A. J. Stevens, J. Amer. chem. Soc. 69, 726 (1947); J. Amer. chem. Soc. 72, 3178 (1950); J. Amer. chem. Soc. 75, 1513 (1953).
- 6 J. Goubeau and R. Warncke, Z. anorg. allg. Chem. 259, 109 (1949).
- 7 F. K. Scholl, Ph. D. Thesis, Technische Hochschule Stuttgart, 1960.
- 8 A. Weiss, G. Nagorsen, and A. Weiss, Z. anorg. allg. Chem. 273, 151 (1953).
- 9 S. Fried, F. Hagemann, and W. H. Zachariasen, J. Amer. chem. Soc. 72, 772 (1950).
- 10 A. I. Popov and G. E. Knudson, J. Amer. chem. Soc. 76, 3921 (1954).
- 11 A. Zalkin and T. H. Templeton, J. Amer. chem. Soc. 75, 2453 (1953).
- 12 L. K. Frevel and H. W. Rinn, Acta crystallogr. 9, 626 (1956).
- 13 K. S. Vorres and F. B. Dutton, J. Amer. chem. Soc. 77, 2019 (1955).
- 14 K. Dehnicke, unpublished work.
- 15 K. S. Vorres and J. Donohue, Acta crystallogr. 8, 25 (1955).
- 16 F. A. Bannister and M. H. Hey, Mineralog. Mag. J. mineralog. Soc. 24, 49 (1935).
- 17 L. G. Sillen, Svensk. kem. Tidskr. 53, 39 (1941).
- 18 W. H. Zachariasen, Acta crystallogr. 2, 388 (1949).
- 19 B. B. Cunningham, Microchem. J., Symposium Issue, p. 69–93 (1961).
- 20 L. G. Sillen and A.-L. Nylander, Svensk. kem. Tidskr. 53, 367 (1941).
- 21 F. H. Kruse, L. B. Asprey, and B. Morosin, Acta crystallogr. 14, 541 (1961).
- 22 L. B. Asprey and F. H. Kruse, J. inorg. nuclear Chem. 13, 32 (1960).
- 23 P. Schmid, Z. anorg. allg. Chem. 167, 369 (1927).
- 24 E. Chauvenet, C.R. hebd. Séances Acad. Sci. 154, 821 (1912).
- 25 S. Takagi, J. chem. Soc. Japan, Pure Chem. Sect. 75, 637 (1954).
- 26 H. Schäfer and H. Bosch (1952), unpublished work.
- 27 H. Schäfer, Angew. Chem. 71, 157 (1959).
- 28 German patent 1017601 (1959), Inventor: W. Schornstein and F. Kern.
- 29 H. Schäfer, Z. anorg. allg. Chem. 260, 279 (1949).
- 30 H. Bärnighausen, J. prakt. Chem. 14, 313 (1961).
- 31 J. Karle, cited by W. H. Zachariasen, Acta crystallogr. 4, 231 (1951).
- 32 F. Fairbrother, A. H. Cowley, and N. Scott, J. less-common Metals 1, 206 (1959).
- 33 H. Schäfer, Angew. Chem. 73, 11 (1961); H. Schäfer: Chemische Transportreaktionen. Verlag Chemie, Weinheim/Bergstr. 1962.
- 34 F. Hund, Z. anorg. allg. Chem. 265, 62 (1951).
- 35 W. Klemm and H. A. Klein, Z. anorg. allg. Chem. 248, 167 (1941).
- 36 W. Finkelburg and A. Stein, J. chem. Physics 18, 1296 (1950).
- 37 W. H. Zachariasen, Acta crystallogr. 4, 231 (1951).
- 38 B. B. Cunningham, D. C. Feay, and M. A. Rollier, J. Amer. chem. Soc. 76, 3361 (1954).
- 39 H. Schäfer and E. Sibbing, Z. anorg. allg. Chem. 305, 341 (1960).
- 40 K. Dehnicke, Angew. Chem. 73, 535 (1961).
- 41 H. Schäfer and F. Kahlenberg, Z. anorg. allg. Chem. 305, 327 (1960).
- 42 H. Schäfer, E. Sibbing, and R. Gerken, Z. anorg. allg. Chem. 307, 163 (1961).
- 43 H. Schäfer, F. Wartenpfuhl, and E. Weise, Z. anorg. allg. Chem. 295, 268 (1958).
- 44 H. Schäfer and F. Wartenpfuhl, J. less-common Metals 3, 29 (1961).
- 45 H. Schäfer and F. Wartenpfuhl, Z. anorg. allg. Chem. 308, 282 (1961).
- 46 P. Ehrlich and H.-J. Seifert, Z. anorg. allg. Chem. 301, 282 (1959).
- 47 A. Brukl and K. Ziegler, Ber. dtsch. chem. Ges. 65, 916 (1932).
- 48
P. Baumgarten and
W. Bruns,
Ber. dtsch. chem. Ges.
72, 1753
(1939).
10.1002/cber.19390720921 Google Scholar
- 49 J. Goubeau and H. Keller, Z. anorg. allg. Chem. 267, 1 (1951).
- 50 E. Thilo and P. Flögel, Angew. Chem. 69, 754 (1957); Z. an-org. allg. Chem. 329, 244 (1964).
- 51 H. D. Fisher, W. J. Lehmann, and I. Shapiroz, J. physic. Chem. 65, 1166 (1961).
- 52 P. Hagenmuller, J. Rouxel and B. LeNeidre, C.R. hebd. Séances Acad. Sci. 252, 282 (1961).
- 53 H. Hahn and H. Katscher, Z. anorg. allg. Chem. 321, 85 (1963).
- 54 P. Ehrlich and W. Engel, Naturwissenschaften 48, 716 (1961).
- 55 P. Ehrlich and W. Engel, Z. anorg. allg. Chem. 317, 21 (1962).
- 56 O. Ruff and H. Lickfett, Ber. dtsch. chem. Ges. 44, 506 (1911).
- 57 F. Wedekind and C. Horst, Ber. dtsch. chem. Ges. 45, 262 (1912).
- 58 H. Schäfer, F. E. Wittig, and W. Wilborn, Z. anorg. allg. Chem. 297, 48 (1958).
- 59 P. Hagenmuller, J. Rouxel, J. David, and A. Colin, Z. anorg. allg. Chem. 323, 1, (1963).
- 60 F. Seel and G. Simon, Angew. Chem. 72, 709 (1960).
- 61 W. C. Smith and V. A. Engelhardt, J. Amer. chem. Soc. 82, 3838 (1960).
- 62 H. Schäfer and R. Gerken, Z. anorg. allg. Chem. 317, 105 (1962).
- 63
K. Dehnicke,
Angew. Chem.
76, 578
(1964);
10.1002/ange.19640761331 Google ScholarAngew. Chem. internat. Edit. 3, 646 (1964).
- 64 K. Huber and J. Baunok, Chimia 15, 365 (1961).
- 65 A. E. Arppe, Poggendorfs Ann. Physik Chem. 64, 246 (1845).
- 66 L. G. Sillen and M. Edstrand, Z. Kristallogr., Mineralog. Petrogr. Abt. 104, 178 (1942).
- 67 E. L. Muetterties and D. D. Coffman, J. Amer. chem. Soc. 80, 5914 (1958).
- 68 H. Hecht, G. Jander, and H. Schlapmann, Z. anorg. allg. Chem. 254, 255 (1947).
- 69 H. Hecht, G. Jander, and H. Schlapmann, Z. anorg. allg. Chem. 254, 260 (1947).
- 70 H. Hecht, G. Jander, and H. Schlapmann, Z. anorg. allg. Chem. 267, 213 (1952).
- 71 D. E. Sands, A. Zalkin, and R. F. Elson, Acta crystallogr. 12, 21 (1959).
- 72 M. Chaigneau, C.R. hebd. Séances. Akad. Sci. 248, 3173 (1959).
- 73 A. Michael and A. Murphy, J. Amer. chem. Soc. 44, 382 (1910).
- 74 M. Pouraud and M. Chaigneau, C.R. hebd. Séances Acad. Sci. 249, 2568 (1959).
- 75 L. E. Trevorrow, J. physic. Chem. 62, 362 (1958).
- 76 M. A. Hepworth and P. L. Robinson, J. inorg. nuclear Chem. 4, 274 (1957).
- 77 G. D. Flesch and H. J. Svec, J. Amer. chem. Soc. 80, 3189 (1958).
- 78 E. E. Aynsley and M. L. Hair, J. chem. Soc. (London) 1958, 3747.
- 79 K. Dehnicke and M. Afify, unpublished work.
- 80 F. A. Cotton, J. W. George, and J. S. Waugh, J. chem. Physics 28, 994 (1958).
- 81 J. A. Rolfe, L. A. Woodward, and D. A. Long, Trans. Faraday Soc. 49, 1388 (1953).
- 82 K. Dehnicke and J. Weidlein, Z. anorg. allg. Chem. 323, 267 (1963).
- 83 H. L. Krauss and F. Schwarzbach, Chem. Ber. 94, 1205 (1961).
- 84 N. V. Sidgwick: The Chemical Elements and their Compounds. Clarendon Press, Oxford 1950, pp. 718, 1044.
- 85 P. L. Robinson and N. Bartlett, J. chem. Soc. (London) 1961, 3549.
- 86 C. W. Koch and R. J. Borg, cited by D. H. Templeton and C. H. Dauben, J. Amer. chem. Soc. 75, 6069 (1953).
- 87 C. W. Koch, cited by D. H. Templeton and C. H. Dauben, J. Amer. chem. Soc. 75, 4560 (1953).
- 88
H. v. Wartenberg,
Z. anorg. allg. Chem.
247, 135
(1941).
10.1002/zaac.19412470112 Google Scholar
- 89 A. Engelbrecht and A. v. Grosse, J. Amer. chem. Soc. 76, 2042 (1954).
- 90 M. Schmeisser, Z. anorg. allg. Chem. 255, 33 (1948).
- 91 F. Seel and I. Nogrady, Z. anorg. allg. Chem. 269, 188 (1952).
- 92 H. L. Krauss and K. Stark, Z. Naturforsch. 17b, 1 (1962).
- 93 I. A. Glukhov and L. A. Tikhomirow, Dokl. Akad. Nauk U.S.S.R. 3, No. 2, 19 (1960); Chem. Abstr. 56, 9690 (1962).
- 94 H. A. Lehmann and L. Kolditz, Z. anorg. allg. Chem. 272, 73 (1953).
- 95 A. Simon and R. Lehmann, Z. anorg. allg. Chem. 311, 224 (1961).
- 96 H. C. Clark and H. J. Emeléus, J. chem. Soc. (London) 1958, 192.
- 97 O. Ruff and H. Lickfett, Ber. dtsch. chem. Ges. 44, 2539 (1911).
- 98 G. Govaert and M. Hansens, Natuurwetensch. Tijdschr. 20, 77 (1938).
- 99 M. J. Frazer and W. Geraard. Chem. and Ind. 1954, 280.
- 100 R. Paetzold and K. Aurich, Z. anorg. allg. Chem. 315, 72 (1962).
- 101 H. J. Emeléus and J. F. Wood, J. chem. Soc. (London) 1948 2183.
- 102 A. Engelbrecht and A. v. Grosse, J. Amer. chem. Soc. 74, 5262 (1952).
- 103 H. A. Leary and J. F. Suttle in: Inorganic Syntheses. McGraw-Hill, New-York-Toronto-London 1957, Vol. V, p. 148.
- 104 C. J. Wolf, A. F. Clifford, and W. H. Johnston, J. Amer. chem. Soc. 79, 4257 (1957).
- 105 R. Colton, J. chem. Soc. (London) 1962, 2078.
- 106 E. E. Aynsley, R. D. Peacock, and P. L. Robinson, J. chem. Soc. (London) 1950, 1622.
- 107 J. H. Holloway and R. D. Peacock, J. chem. Soc. (London) 1963, 527.
- 108 A. J. Edwards, Proc. chem. Soc. (London) 1963, 205.
- 109 P. Spring, Bull. Acad. Sci. Belgique 2, 39, 895 (1875).
- 109a K. Dehnicke, Naturwissenschaften 51, 535 (1964).
- 110 K. Dehnicke, Z. anorg. allg. Chem. 312, 237 (1961).
- 111 K. Dehnicke and J. Weidlein, unpublished work.
- 112 K. Dehnicke in G. Brauer: Handbuch der Präparativen An-organischen Chemie. F. Enke-Verlag, Stuttgart 1962, Vol 2, p. 1107.
- 113 K. Dehnicke, Z. anorg. allg. Chem. 308, 72 (1961).
- 113a K. Dehnicke, Z. anorg. allg. Chem. 309, 266 (1961).
- 114 K. Dehnicke, Lecture at the XVII. IUPAC Congress, München (Germany) 1959, No. A 1042.
- 115 K. Dehnicke and K.-U. Meyer, Z. anorg. allg. Chem. 331, 121 (1964).
- 116 L. Dorn, Ph. D. Thesis, Technische Hochschule Stuttgart, 1963.
- 117 K. Dehnicke, Angew. Chem. 73, 763 (1961).
- 118 K. Dehnicke, Angew. Chem. 74, 495 (1962).
- 119 J. Weidlein, Diploma Thesis, Technische Hochschule Stuttgart, 1962.
- 120 K. Dehnicke, Angew. Chem. 75, 419 (1963); Angew. Chem. internat. Edit. 2, 325 (1963).
- 121 H. Martin and T. Jacobsen, Angew. Chem. 67, 524 (1955); Z. physik. Chem. NF 17, 375 (1958).
- 122 M. Schmeißer, W. Fink, and K. Brändle, Angew. Chem. 69, 780 (1957).
- 123 K. Brändle, M. Schmeißer, and W. Lüttke, Chem. Ber. 93, 2300 (1960).
- 124 A. J. Arvia, L. F. R. Cafferata, and H. J. Schumacher, Chem. Ber. 96, 1187 (1963).
- 125 M. Schmeißer, W. Fink, and K. Brändle, cited by G. Brauer: Handbuch der Präparativen Anorganischen Chemie. F. Enke-Verlag, Stuttgart 1962, Vol 1, p. 298.
- 126
K. Dehnicke,
Angew. Chem.
76, 385
(1964);
10.1002/ange.19640760925 Google ScholarAngew. Chem. internat. Edit. 3, 448 (1964).
- 127 K. Dehnicke, J. Weidlein, and K. Krogmann, Angew. Chem. 75, 1110 (1963); Angew. Chem. internat. Edit. 3, 142 (1964).
